The samples of Sunflower stalks were collected from Behshar and Neka. The average fiber length, cell wall diameter and thickness measured were 0.9581lm, 23.605 and 5.927µm respectively. The components of chemical and depithed stalk including: cellulose, lignin, ash and extractives content using Alchol-Aceton and NaOH 1% were measured as 39.93, 22.24, 12.49,4.92,36.10% and 47.37, 21.20, 7.50, 3.61, 34.00%, respectively. The following optimum conditions were selected regarding of pulp yield 43.80% and kappa number 82.55: with cooked chemical substances: 20% Na2o applied, on the basis of dry sunflower stalk, pulping temperature: 170°C and residence time at maximum temperature: l80min. Pulp refining carried out with PFI revolutions 150 and 500 RPM up to freeness 372 and 328ml CSF, respectively. Statistical analysis showed that physical and mechanical, properties of hand sheets with basis weight 127gr/m2 NSSC pulp made from Sunflower stalk with freeness 328ml CSF are better than mixed hardwood NSSC pulp (except burst index) and NSSC pulp of Sunflower stalk with freeness 372ml CSF. Furthermore, no significant difference was observed between mixed hardwood NSSC pulp and NSSC pulp of Sunflower stalk with freeness 372ml CSF.