D-Optimal Design Optimization for Esterification of Palm Fatty Acids Distillate with Polyhydric Alcohols for Biolubricants Production

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

Ahmed Jumaah Majd; SALIH NADIA; SALIMON JUMAT

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2022 | Volume:41 | Issue:5 Page(s): 1657-1672

Download Full-Text

View:

Download:

Cites:

Information Journal Paper

Title

D-Optimal Design Optimization for Esterification of Palm Fatty Acids Distillate with Polyhydric Alcohols for Biolubricants Production

Author(s)

Ahmed Jumaah Majd | SALIH NADIA | SALIMON JUMAT | Issue Writer Certificate

Keywords

Palm fatty acid distillate

D-optimal design

Biolubricants

Response surface methodology

Abstract

Plant-based bio-lubricant is crucial to be developed and adopted by many industries. This is due to the presence of toxicity risk, climate change, energy security as well greenenvironmental approach issues. The utilization of palm oil processing industries' by-product, Palm fatty acid distillate (PFAD-based bio-lubricants is one way of a green environment approach. A synthesis of polyol esters based on PFAD for bio-lubricants was carried out. The esterification of PFAD with high-degree polyhydric alcohols trimethylolpropane (TMP), di-trimethylopropane (di-TMP), pentaerythritol (PE), and di-pentaerythritol (Di-PE) in the presence of sulphuric acid (H2SO4) catalyst have been performed. The optimization of the esterification reaction process was evaluated using a D-optimal design based on three reaction parameters,H2SO4 concentration (%) for the catalyst, esterification time (h), and esterification temperature (°, C). The chemical structure of the synthesized polyol esters was characterized and confirmed by using FT-IR and NMR (1H and 13C) spectroscopies. The results showed that PFAD-based polyesters of PFAD-TMP ester successfully produced high yields of 93% compared to others. The synthesized PFAD-based polyesters showed good lubrication properties with high viscosity indices in the range of 141-187, pour points (-5 to 5 º, C), flash points (230-360 º, C), and oxidative stability temperature (188-301 °, C), respectively. The ester functional group present in the chemical structure of PFAD-based polyesters showed a positive impact on the lubrication properties. The study indicated that PFAD-based polyesters are plausible to be used in industrial bio-lubricant applications.

Multimedia

No record.

Cites

No record.

References

No record.

Cite

APA: Copy

Ahmed Jumaah, Majd, SALIH, NADIA, & SALIMON, JUMAT. (2022). D-Optimal Design Optimization for Esterification of Palm Fatty Acids Distillate with Polyhydric Alcohols for Biolubricants Production. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 41(5), 1657-1672. SID. https://sid.ir/paper/1039836/en

Vancouver: Copy

Ahmed Jumaah Majd, SALIH NADIA, SALIMON JUMAT. D-Optimal Design Optimization for Esterification of Palm Fatty Acids Distillate with Polyhydric Alcohols for Biolubricants Production. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2022;41(5):1657-1672. Available from: https://sid.ir/paper/1039836/en

IEEE: Copy

Majd Ahmed Jumaah, NADIA SALIH, and JUMAT SALIMON, “D-Optimal Design Optimization for Esterification of Palm Fatty Acids Distillate with Polyhydric Alcohols for Biolubricants Production,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 41, no. 5, pp. 1657–1672, 2022, [Online]. Available: https://sid.ir/paper/1039836/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops