Synthesis and characterization of mononuclear oxime palladacycles based phosphorus ligands, and evaluation of their catalytic and cytotoxicity activities

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

Samiee Sepideh; Shiralinia Ahmadreza; Hoveizi Elham

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: APPLIED CHEMISTRY TODAY Year:2024 | Volume:19 | Issue:72 Page(s): 113-126

Download Full-Text

Persian Verion

View:

Download:

Cites:

Information Journal Paper

Title

Synthesis and characterization of mononuclear oxime palladacycles based phosphorus ligands, and evaluation of their catalytic and cytotoxicity activities

Author(s)

Samiee Sepideh | Shiralinia Ahmadreza | Hoveizi Elham | Issue Writer Certificate

Keywords

Oxime palladacycle

Phosphorus ligand

Catalytic activity

Suzuki reaction

Cytotoxicity activity

Abstract

In the present investigation, a new series of mononuclear oxime palladacycles based on phosphorus ylides with the empirical formula [Pd{N,N'-C5H4{C(H)=NO}-2}(Ph2PCH2PPh2C(H)C(O)C6H4X)]ClO4 (X = Cl (1), Br (2), NO2(3) and OCH3 (4)) were synthesized. These complexes were formed through a cleavage chloro-bridges reaction of the dinuclear palladacycle complex in the presence of phosphorous ligands using sodium perchlorate and dichloromethane solvent. The synthesized complexes were characterized by elemental analysis, 31P NMR, 1H NMR, 13C NMR, and FT-IR spectroscopic methods. The obtained results of NMR and IR spectroscopes confirmed the synthesis of new mononuclear palladacycle complexes and the P,C-coordination mode connection for asymmetric phosphorus ylides. In addition, the catalytic activity of the synthesized complexes in the carbon-carbon coupling reaction and cytotoxic effect on A549, HT-29, and 1321N1 cell lines using the MTT-assay method. The results of this research can be promising for the use of these compounds as catalysts in the Suzuki–Miyaura carbon-carbon coupling reaction and anticancer agents.

Multimedia

No record.

Cites

No record.

References

No record.

Cite

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans