DIOXOMOLYBDENUM (VI) COMPLEXES WITH O-PHENYLENEDIAMINE AND 4-METHYL-O- PHENYLENEDIAMINE LIGANDS: SYNTHESIS AND CATALYTIC ACTIVITY IN OXIDATION OF ALCOHOLS

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RANJINEH KHOJASTEH ROYA; MIRAHMADI SEYEDEH DELARAM

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Journal: Journal of Applied Research in Chemistry Year:2009 | Volume:3 | Issue:10 Page(s): 49-53

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Title

DIOXOMOLYBDENUM (VI) COMPLEXES WITH O-PHENYLENEDIAMINE AND 4-METHYL-O- PHENYLENEDIAMINE LIGANDS: SYNTHESIS AND CATALYTIC ACTIVITY IN OXIDATION OF ALCOHOLS

Author(s)

RANJINEH KHOJASTEH ROYA | MIRAHMADI SEYEDEH DELARAM | Issue Writer Certificate

Keywords

DIOXOMOLYBDENUM (VI) COMPLEXESQ3

DIAMINE LIGANDSQ3

STRUCTURESQ3

OXIDATION CATALYSISQ3

Abstract

Two new dioxomolybdenum (VI) complexes [MoO2 (acac) LL'] (I) and [MoO2L2L2"] (II) [L=OC (CH3) CHCOCH3, L'=NH2C6H4NH2, L"=NH2C6H3CH3NH2] with diamine o-Phenylenediamine (OPDA) and 4- Methyl-o-Phenylenediamine (4-Me-OPDA) ligands have been synthesized and characterized. Compounds (I) (61% yield) and (II) (62% yield) were obtained from the reactions of MoO2 (acac)2 [acac=acetyl acetonato] with 1 equiv. of OPDA and 4-Me-OPDA.1H, 13C NMR, IR spectral data indicated that the ligands acted as unidentate and STRUCTURES of both compounds were six-coordinated. The dioxomolybdenum (VI) complexes (I) and (II) are efficient catalysts for oxidation of alcohols with H2O2 as an oxidant.

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APA: Copy

RANJINEH KHOJASTEH, ROYA, & MIRAHMADI, SEYEDEH DELARAM. (2009). DIOXOMOLYBDENUM (VI) COMPLEXES WITH O-PHENYLENEDIAMINE AND 4-METHYL-O- PHENYLENEDIAMINE LIGANDS: SYNTHESIS AND CATALYTIC ACTIVITY IN OXIDATION OF ALCOHOLS. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 3(10), 49-53. SID. https://sid.ir/paper/180065/en

Vancouver: Copy

RANJINEH KHOJASTEH ROYA, MIRAHMADI SEYEDEH DELARAM. DIOXOMOLYBDENUM (VI) COMPLEXES WITH O-PHENYLENEDIAMINE AND 4-METHYL-O- PHENYLENEDIAMINE LIGANDS: SYNTHESIS AND CATALYTIC ACTIVITY IN OXIDATION OF ALCOHOLS. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2009;3(10):49-53. Available from: https://sid.ir/paper/180065/en

IEEE: Copy

ROYA RANJINEH KHOJASTEH, and SEYEDEH DELARAM MIRAHMADI, “DIOXOMOLYBDENUM (VI) COMPLEXES WITH O-PHENYLENEDIAMINE AND 4-METHYL-O- PHENYLENEDIAMINE LIGANDS: SYNTHESIS AND CATALYTIC ACTIVITY IN OXIDATION OF ALCOHOLS,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 3, no. 10, pp. 49–53, 2009, [Online]. Available: https://sid.ir/paper/180065/en

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