ADSORPTION OF CARBON MONOXIDE, HYDROGEN AND METHANE ON CARBON MOLECULAR SIEVE

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BOZORG ZADEH H.R.; MOUSAVI Z.; GHASEMI M.R.

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Journal: Journal of Applied Research in Chemistry Year:2014 | Volume:8 | Issue:1 Page(s): 5-12

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Title

ADSORPTION OF CARBON MONOXIDE, HYDROGEN AND METHANE ON CARBON MOLECULAR SIEVE

Author(s)

BOZORG ZADEH H.R. | MOUSAVI Z. | GHASEMI M.R. | Issue Writer Certificate

Keywords

ADSORPTIONQ2

CARBON MOLECULAR SIEVEQ2

LANGMUIR ISOTHERMQ2

KINETIC MODELQ2

Abstract

Separation of carbon monoxide, hydrogen and methane from gas mixtures is an important industrial process. In this work, the ADSORPTION capacity of CARBON MOLECULAR SIEVE (CMS) for these gases was studied by volumetric method at temperature of 20oC and pressure in the range of 200- 3500 kPa. Maximum ADSORPTION of carbon monoxide, hydrogen and methane was 6.98, 3.39 and 2.77 mmol.g-1, respectively. ADSORPTION isotherms of these gases by using Excel showed to be a Langmuir type ADSORPTION. Gas ADSORPTION rate was calculated and showed that carbon monoxide, hydrogen and methane ADSORPTIONs by CMS were based on the difference between their ADSORPTION rates and followed a kinetic rate of pseudo second-order. The maximum volume of ADSORPTION gas of micro pores and potential energy as the parameter for predicting the type of ADSORPTION were calculated using Dubinin-Radushkevich (DR) method. ADSORPTION potential energy for carbon monoxide, hydrogen and methane were in the order of 7.95, 7.78 and 7.79 kJ.mol-1.

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APA: Copy

BOZORG ZADEH, H.R., MOUSAVI, Z., & GHASEMI, M.R.. (2014). ADSORPTION OF CARBON MONOXIDE, HYDROGEN AND METHANE ON CARBON MOLECULAR SIEVE. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), 8(1), 5-12. SID. https://sid.ir/paper/180245/en

Vancouver: Copy

BOZORG ZADEH H.R., MOUSAVI Z., GHASEMI M.R.. ADSORPTION OF CARBON MONOXIDE, HYDROGEN AND METHANE ON CARBON MOLECULAR SIEVE. JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC)[Internet]. 2014;8(1):5-12. Available from: https://sid.ir/paper/180245/en

IEEE: Copy

H.R. BOZORG ZADEH, Z. MOUSAVI, and M.R. GHASEMI, “ADSORPTION OF CARBON MONOXIDE, HYDROGEN AND METHANE ON CARBON MOLECULAR SIEVE,” JOURNAL OF APPLIED RESEARCHES IN CHEMISTRY (JARC), vol. 8, no. 1, pp. 5–12, 2014, [Online]. Available: https://sid.ir/paper/180245/en

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