SOLVENT EFFECTS ON TAUTOMERIC AND MICROSCOPIC PROTONATION CONSTANTS OF GLYCINE IN DIFFERENT AQUEOUS SOLUTIONS OF 1, 4-DIOXANE

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MOJARRAD M.S.; SHAMEL A.; GHARIB F.

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Journal: JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY Year:2012 | Volume:9 | Issue:1 Page(s): 41-50

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Title

SOLVENT EFFECTS ON TAUTOMERIC AND MICROSCOPIC PROTONATION CONSTANTS OF GLYCINE IN DIFFERENT AQUEOUS SOLUTIONS OF 1, 4-DIOXANE

Author(s)

MOJARRAD M.S. | SHAMEL A. | GHARIB F. | Issue Writer Certificate

Keywords

GLYCINEQ2

MICRO AND MACRO PROTONATION AND TAUTOMERIC CONSTANTSQ2

1Q2

4-DIOXANEQ2

SOLVENT EFFECTQ2

Abstract

The acid-base equilibria of GLYCINE have been studied in different aqueous solutions of 1, 4-DIOXANE (0-50% by v/v) using potentiometric method. In this study, the macro and micro protonation constants of the amino acid and its tautomeric constant have been determined at 25oC and constant ionic strength 0.1 mol dm-3 (NaCl). The protonation and the tautomeric constants of GLYCINE in different binary mixtures were analyzed in terms of Kamlet, Abboud and Taft (KAT) parameters.Single-parameter correlations of the constants versus a (hydrogen-bond donor acidity), b (hydrogenbond acceptor basicity) and p* (dipolarity/polarizability) are poor in all solutions. Multi-parameter correlations show better results, but dual-parameter correlations represent significant improvements with regard to the single- and multi-parameter models. Linear correlation is observed when the experimental protonation constant values are plotted versus the calculated ones, while the KAT parameters are considered. Finally, the results are discussed in terms of the effect of the solvent on protonation and tautomeric constants.

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APA: Copy

MOJARRAD, M.S., SHAMEL, A., & GHARIB, F.. (2012). SOLVENT EFFECTS ON TAUTOMERIC AND MICROSCOPIC PROTONATION CONSTANTS OF GLYCINE IN DIFFERENT AQUEOUS SOLUTIONS OF 1, 4-DIOXANE. JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY, 9(1), 41-50. SID. https://sid.ir/paper/207665/en

Vancouver: Copy

MOJARRAD M.S., SHAMEL A., GHARIB F.. SOLVENT EFFECTS ON TAUTOMERIC AND MICROSCOPIC PROTONATION CONSTANTS OF GLYCINE IN DIFFERENT AQUEOUS SOLUTIONS OF 1, 4-DIOXANE. JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY[Internet]. 2012;9(1):41-50. Available from: https://sid.ir/paper/207665/en

IEEE: Copy

M.S. MOJARRAD, A. SHAMEL, and F. GHARIB, “SOLVENT EFFECTS ON TAUTOMERIC AND MICROSCOPIC PROTONATION CONSTANTS OF GLYCINE IN DIFFERENT AQUEOUS SOLUTIONS OF 1, 4-DIOXANE,” JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY, vol. 9, no. 1, pp. 41–50, 2012, [Online]. Available: https://sid.ir/paper/207665/en

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