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Information Journal Paper

Title

(1E,2E) -BIS (2-AMINOPHENYL) N'1,N'2-DIHYDROXYETHANE BIS (IMIDOTHIOATE) AS A NEUTRAL CARRIER IN ION-SELECTIVE ELECTRODE FOR NI(II) AND IT COMPUTATIONAL STUDIES

Pages

  191-197

Keywords

NI (II) DETERMINATIONQ2

Abstract

 A PVC MEMBRANE Ni (II) ION SELECTIVE ELECTRODE has been constructed using (1E, 2E) -bis (2-aminophenyl) N'1, N'2-dihydroxyethanebis as membrane carrier. The electrode exhibited a good potentiometric response for Ni (II) over a wide concentration range 1.0×10-4 to 1.0×10-1M with a slope of 29.4±0.5 mV/decade a and a working pH range of 6.5-9.0. It had a fast response time of£20s. The best performance was observed with the membrane having 30.5% PVC, 3.0% ligand, 61.0% acetophenone and 5.5% oleic acid composition.In this work, the ligand structure studied by ab initio HF calculations using a standard 6-31G* basis set and LanL2DZ.

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  • Cite

    APA: Copy

    FEKRI, M.H., & DARVISHPOUR, M.. (2012). (1E,2E) -BIS (2-AMINOPHENYL) N'1,N'2-DIHYDROXYETHANE BIS (IMIDOTHIOATE) AS A NEUTRAL CARRIER IN ION-SELECTIVE ELECTRODE FOR NI(II) AND IT COMPUTATIONAL STUDIES. JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY, 9(3), 191-197. SID. https://sid.ir/paper/207726/en

    Vancouver: Copy

    FEKRI M.H., DARVISHPOUR M.. (1E,2E) -BIS (2-AMINOPHENYL) N'1,N'2-DIHYDROXYETHANE BIS (IMIDOTHIOATE) AS A NEUTRAL CARRIER IN ION-SELECTIVE ELECTRODE FOR NI(II) AND IT COMPUTATIONAL STUDIES. JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY[Internet]. 2012;9(3):191-197. Available from: https://sid.ir/paper/207726/en

    IEEE: Copy

    M.H. FEKRI, and M. DARVISHPOUR, “(1E,2E) -BIS (2-AMINOPHENYL) N'1,N'2-DIHYDROXYETHANE BIS (IMIDOTHIOATE) AS A NEUTRAL CARRIER IN ION-SELECTIVE ELECTRODE FOR NI(II) AND IT COMPUTATIONAL STUDIES,” JOURNAL OF PHYSICAL AND THEORETICAL CHEMISTRY, vol. 9, no. 3, pp. 191–197, 2012, [Online]. Available: https://sid.ir/paper/207726/en

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