SYNTHESIS, 
STRUCTURE, PHOTOLUMINESCENCE AND THEORETICAL STUDY OF 
{(N,N'-DIMETHYL-4,4'-BIPYRIDINIUM)[CD2(μ2-CL)4CL2]}N 
WITH N,N'-DIMETHYL-4,4'-BIPYRIDINIUM GENERATED 
IN SITU

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CHEN W.; YAO Z.; YING S.; LIU D.; LIU J.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:1 Page(s): 180-184

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Title

SYNTHESIS, STRUCTURE, PHOTOLUMINESCENCE AND THEORETICAL STUDY OF {(N,N'-DIMETHYL-4,4'-BIPYRIDINIUM)[CD2(μ2-CL)4CL2]}N WITH N,N'-DIMETHYL-4,4'-BIPYRIDINIUM GENERATED IN SITU

Author(s)

Keywords

CADMIUM

CRYSTAL STRUCTURE

HYDROTHERMAL REACTION

IN SITU

VIOLOGEN

Abstract

The title complex, {(N,N’-dimethyl-4,4’-bipyridinium)[Cd2(m2-Cl)4Cl2]}n (1), in which the N,N'-dimethyl-4,4’-bipyridinium was generated IN SITU, was synthesized via HYDROTHERMAL REACTION. X-Ray diffraction analysis revealed that the structure of 1 consisted of MV2+ (MV2+= N,N'-dimethyl-4,4’-bipyridinium) cationic moieties and infinite [Cd2(m2-Cl)4Cl2]n anionic chains. The CADMIUM atom was bound by one terminal chlorine atom and four m2-bridging chlorine atoms, yielding a slightly distorted triangular bipyramid. Photoluminescent investigation revealed that the complex displayed an emission in greenish blue region.

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APA: Copy

CHEN, W., YAO, Z., YING, S., LIU, D., & LIU, J.. (2010). SYNTHESIS, STRUCTURE, PHOTOLUMINESCENCE AND THEORETICAL STUDY OF {(N,N'-DIMETHYL-4,4'-BIPYRIDINIUM)[CD₂(μ₂-CL)₄CL₂]}_N WITH N,N'-DIMETHYL-4,4'-BIPYRIDINIUM GENERATED IN SITU. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(1), 180-184. SID. https://sid.ir/paper/282435/en

Vancouver: Copy

CHEN W., YAO Z., YING S., LIU D., LIU J.. SYNTHESIS, STRUCTURE, PHOTOLUMINESCENCE AND THEORETICAL STUDY OF {(N,N'-DIMETHYL-4,4'-BIPYRIDINIUM)[CD₂(μ₂-CL)₄CL₂]}_N WITH N,N'-DIMETHYL-4,4'-BIPYRIDINIUM GENERATED IN SITU. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(1):180-184. Available from: https://sid.ir/paper/282435/en

IEEE: Copy

W. CHEN, Z. YAO, S. YING, D. LIU, and J. LIU, “SYNTHESIS, STRUCTURE, PHOTOLUMINESCENCE AND THEORETICAL STUDY OF {(N,N'-DIMETHYL-4,4'-BIPYRIDINIUM)[CD₂(μ₂-CL)₄CL₂]}_N WITH N,N'-DIMETHYL-4,4'-BIPYRIDINIUM GENERATED IN SITU,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 1, pp. 180–184, 2010, [Online]. Available: https://sid.ir/paper/282435/en

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