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Information Journal Paper

Title

SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL MIXED CRYSTAL CONTAINING AN OXORHENIUM(V) AND IMIDORHENIUM(V) COMPLEX

Pages

  775-780

Keywords

OXORHENIUM(V) 

Abstract

 An unusual MIXED CRYSTAL of a SQUARE-PYRAMIDAL oxorhenium(V), [ReOCl(Hdua)], and an octahedral IMIDOrhenium(V) complex, [Re(dua)Cl2(PPh3)], was prepared from the reaction of trans-[ReOCl3(PPh3)2] and (6Z)-6-(2-aminobenzylideneamino)- 5-amino-1,3-dimethylpyrimidine-2,4(1H,3H)-dione (H3dua) in ethanol. Characterization was performed by single crystal X-ray structure determination and IR spectroscopy. The chelate Hdua is coordinated as a tridentate diamido-imine, and dua is chelated as an IMIDO-imino-amide.

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    • Cite

    APA: Copy

    MAYER, P., HOSTEN, E., GERBER, T.I.A., & BOOYSEN, I.. (2010). SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL MIXED CRYSTAL CONTAINING AN OXORHENIUM(V) AND IMIDORHENIUM(V) COMPLEX. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(3), 775-780. SID. https://sid.ir/paper/282466/en

    Vancouver: Copy

    MAYER P., HOSTEN E., GERBER T.I.A., BOOYSEN I.. SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL MIXED CRYSTAL CONTAINING AN OXORHENIUM(V) AND IMIDORHENIUM(V) COMPLEX. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(3):775-780. Available from: https://sid.ir/paper/282466/en

    IEEE: Copy

    P. MAYER, E. HOSTEN, T.I.A. GERBER, and I. BOOYSEN, “SYNTHESIS AND CRYSTAL STRUCTURE OF AN UNUSUAL MIXED CRYSTAL CONTAINING AN OXORHENIUM(V) AND IMIDORHENIUM(V) COMPLEX,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 3, pp. 775–780, 2010, [Online]. Available: https://sid.ir/paper/282466/en

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