SOME NEW UNSYMMETRICAL DIIMINO TETRADENTATE SCHIFF BASE DERIVED FROM 3,4-DIAMINOBENZOPHENONE: SYNTHESIS, CHARACTERIZATION AND THE FORMATION CONSTANT OF NI(II) AND CU(II) COMPLEXES

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ASADI M.; SOTOUDEH KHAH M.

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:4 Page(s): 875-882

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Title

SOME NEW UNSYMMETRICAL DIIMINO TETRADENTATE SCHIFF BASE DERIVED FROM 3,4-DIAMINOBENZOPHENONE: SYNTHESIS, CHARACTERIZATION AND THE FORMATION CONSTANT OF NI(II) AND CU(II) COMPLEXES

Author(s)

ASADI M. | SOTOUDEH KHAH M. | Issue Writer Certificate

Keywords

FORMATION CONSTANT

FREE ENERGY

METAL COMPLEX

THERMODYNAMIC

UNSYMMETRICAL SCHIFF BASE

Abstract

Some new unsymmetrical diimino tetradentate Schiff bases derived from 3, 4-diaminobenzophenone, (N-salicyliden-N'-5- OMe. salycyliden) -3, 4-diaminobenzophenone (H2sal-5-OMe. sal. dabp) (H2L1), (H2sal-5-Br. sal. dabp) (H2L2), (H2sal-5-Cl. sal. dabp) (H2L3) and (H2sal-5-NO2. sal. dabp) (H2L4) and their Ni (II) and Cu (II) complexes were synthesized and characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra and mass spectra. The THERMODYNAMIC FORMATION CONSTANTs of the complexes were determined spectrophotometrically at constant ionic strength (0.1 M NaClO4) at 25oC in DMF and their free energies of formation were calculated at 25oC.

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APA: Copy

ASADI, M., & SOTOUDEH KHAH, M.. (2010). SOME NEW UNSYMMETRICAL DIIMINO TETRADENTATE SCHIFF BASE DERIVED FROM 3,4-DIAMINOBENZOPHENONE: SYNTHESIS, CHARACTERIZATION AND THE FORMATION CONSTANT OF NI(II) AND CU(II) COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(4), 875-882. SID. https://sid.ir/paper/282479/en

Vancouver: Copy

ASADI M., SOTOUDEH KHAH M.. SOME NEW UNSYMMETRICAL DIIMINO TETRADENTATE SCHIFF BASE DERIVED FROM 3,4-DIAMINOBENZOPHENONE: SYNTHESIS, CHARACTERIZATION AND THE FORMATION CONSTANT OF NI(II) AND CU(II) COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(4):875-882. Available from: https://sid.ir/paper/282479/en

IEEE: Copy

M. ASADI, and M. SOTOUDEH KHAH, “SOME NEW UNSYMMETRICAL DIIMINO TETRADENTATE SCHIFF BASE DERIVED FROM 3,4-DIAMINOBENZOPHENONE: SYNTHESIS, CHARACTERIZATION AND THE FORMATION CONSTANT OF NI(II) AND CU(II) COMPLEXES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 4, pp. 875–882, 2010, [Online]. Available: https://sid.ir/paper/282479/en

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