SYNTHESIS AND ELECTROCHEMISTRY OF M(II) N2O2 SCHIFF BASE COMPLEXES: X-RAY STRUCTURE OF {NI[BIS(3-CHLOROACETYLACETONE)ETHYLENEDIIMINE]}

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KIANFAR A.H.; ZARGARI S.; KHAVASI H.R.

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:4 Page(s): 908-916

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Title

SYNTHESIS AND ELECTROCHEMISTRY OF M(II) N2O2 SCHIFF BASE COMPLEXES: X-RAY STRUCTURE OF {NI[BIS(3-CHLOROACETYLACETONE)ETHYLENEDIIMINE]}

Author(s)

KIANFAR A.H. | ZARGARI S. | KHAVASI H.R. | Issue Writer Certificate

Keywords

COBALT(II)

NICKEL(II)

CU(II)

SCHIFF BASE COMPLEXES

ELECTROCHEMISTRY

Abstract

The synthesis and characterization of [Ni (BCE)] and [Cu (BCE)] (where BCE=bis (3-chloroacetylacetone) ethylenediimine) are described. The coordination geometry of [Ni (BCE)] was determined by X-ray crystallography. It was found to be planar and four coordinate in the solid state. The electrochemical properties of M (Chel), where M=Co (II), Ni (II) and Cu (II), and Chel= BAE (bis (acetylacetone) ethylenediimine), BBE=bis (benzoylacetone) ethylenediimine, BFE (bis (1, 1, 1-triflouroacetylacetone) ethylenediimine and BCE ligands were investigated in DMF and DMSO as solvents. The oxidation potentials changed from left to right in the periodic table in the trend: Co< Ni<Cu, while the reduction potentials changed according to the trend: Ni>Co >Cu. The oxidation potentials of M (II) to M (III) (M=Ni and Cu) increased according to the Schiff base ligands in the trend: BAE<BBE<BCE<BFE, while the reduction potentials followed a reverse trend: BAE>BE>BCE>BFE. The oxidation potentials of M (II) to M (III) increased according to the solvent in the trend: DMSO<DMF.

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APA: Copy

KIANFAR, A.H., ZARGARI, S., & KHAVASI, H.R.. (2010). SYNTHESIS AND ELECTROCHEMISTRY OF M(II) N₂O₂SCHIFF BASE COMPLEXES: X-RAY STRUCTURE OF {NI[BIS(3-CHLOROACETYLACETONE)ETHYLENEDIIMINE]}. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(4), 908-916. SID. https://sid.ir/paper/282481/en

Vancouver: Copy

KIANFAR A.H., ZARGARI S., KHAVASI H.R.. SYNTHESIS AND ELECTROCHEMISTRY OF M(II) N₂O₂SCHIFF BASE COMPLEXES: X-RAY STRUCTURE OF {NI[BIS(3-CHLOROACETYLACETONE)ETHYLENEDIIMINE]}. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(4):908-916. Available from: https://sid.ir/paper/282481/en

IEEE: Copy

A.H. KIANFAR, S. ZARGARI, and H.R. KHAVASI, “SYNTHESIS AND ELECTROCHEMISTRY OF M(II) N₂O₂SCHIFF BASE COMPLEXES: X-RAY STRUCTURE OF {NI[BIS(3-CHLOROACETYLACETONE)ETHYLENEDIIMINE]},” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 4, pp. 908–916, 2010, [Online]. Available: https://sid.ir/paper/282481/en

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