SYNTHESIS AND CHARACTERIZATION OF CD(II) MACROCYCLIC SCHIFF BASE COMPLEX WITH TWO 2-AMINOETHYL PENDANT ARMS

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KEYPOUR H.; DEHGHANI FIROUZABADI A.A.; REZAEI VALA M.; GOUDARZI AFSHAR H.

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2010 | Volume:7 | Issue:4 Page(s): 820-824

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Title

SYNTHESIS AND CHARACTERIZATION OF CD(II) MACROCYCLIC SCHIFF BASE COMPLEX WITH TWO 2-AMINOETHYL PENDANT ARMS

Author(s)

KEYPOUR H. | DEHGHANI FIROUZABADI A.A. | REZAEI VALA M. | GOUDARZI AFSHAR H. | Issue Writer Certificate

Keywords

MACROCYCLIC COMPLEX

SCHIFF BASE

CADMIUM(II)

PENDANT ARM

AB INITIO

Abstract

A new PENDANT ARMed SCHIFF BASE MACROCYCLIC COMPLEX of [CdL] 2+, was prepared via cyclocondensation of 2, 6-bis (2- formylphenoxymethyl) pyridine with branched hexaamine in the presence of Cd (II) ion. The ligand was 23-membered oxaazamacrocycle having two 2-aminoethyl PENDANT ARMs [L: 3, 28-dioxa-14, 17-bis (aminoethyl) -11, 14, 17, 20, 34- pentaazatetracyclo [34.3.1] tetratriacontane-1 (34), 4, 6, 8, 10, 20, 22, 24, 26, 30, 32-undecaene]. The complex was investigated by IR, 1H NMR, microanalysis and MALDI mass spectroscopy. The structure of the complex was verified by AB INITIO HF-MO calculations using a standard 3-21G* basis set. This article introduces an unusual seven-membered chelate ring and shows that by its using, the Cd-N bonds lengths within the macrocycle would be longer and also Cd (II) -pendant amine bonds lengths would be shorter.

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APA: Copy

KEYPOUR, H., DEHGHANI FIROUZABADI, A.A., REZAEI VALA, M., & GOUDARZI AFSHAR, H.. (2010). SYNTHESIS AND CHARACTERIZATION OF CD(II) MACROCYCLIC SCHIFF BASE COMPLEX WITH TWO 2-AMINOETHYL PENDANT ARMS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 7(4), 820-824. SID. https://sid.ir/paper/282500/en

Vancouver: Copy

KEYPOUR H., DEHGHANI FIROUZABADI A.A., REZAEI VALA M., GOUDARZI AFSHAR H.. SYNTHESIS AND CHARACTERIZATION OF CD(II) MACROCYCLIC SCHIFF BASE COMPLEX WITH TWO 2-AMINOETHYL PENDANT ARMS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2010;7(4):820-824. Available from: https://sid.ir/paper/282500/en

IEEE: Copy

H. KEYPOUR, A.A. DEHGHANI FIROUZABADI, M. REZAEI VALA, and H. GOUDARZI AFSHAR, “SYNTHESIS AND CHARACTERIZATION OF CD(II) MACROCYCLIC SCHIFF BASE COMPLEX WITH TWO 2-AMINOETHYL PENDANT ARMS,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 7, no. 4, pp. 820–824, 2010, [Online]. Available: https://sid.ir/paper/282500/en

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