ELECTRON TRANSFER REACTIONS ASSOCIATED WITH ETHYL VIOLOGEN-β-CYCLODEXTRIN COMPLEXATION: EQUILIBRIUM AND KINETIC ASPECTS

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SHAZIA AKBAR; NAQVI I.I.; MOHAMMAD M.

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Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2014 | Volume:11 | Issue:3 Page(s): 615-621

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Title

ELECTRON TRANSFER REACTIONS ASSOCIATED WITH ETHYL VIOLOGEN-β-CYCLODEXTRIN COMPLEXATION: EQUILIBRIUM AND KINETIC ASPECTS

Author(s)

SHAZIA AKBAR | NAQVI I.I. | MOHAMMAD M. | Issue Writer Certificate

Keywords

VIOLOGEN

?CD SYSTEM

INCLUSION COMPLEX

CYCLIC VOLTAMMETRY

DIGITAL SIMULATION

Abstract

Formation of the complex of ethyl VIOLOGEN in its cationic (Ev+) and neutral (Ev∘) forms with β-cyclodextrin (b-CD) was investigated by means of voltammetric technique in buffer solution of pH 7.00. The number of bCD (n or m) per VIOLOGEN species (Ev+) or (Ev∘), bonding equilibrium constants as well as bonding rate constants was calculated. The calculated values ofK (1) eqandK (2) eq (pertaining to the bonding of Ev+and Ev∘ with bCD) are 13.6 M–n and 2.1×103 M−m , respectively, whereas the calculated values of n and m are 0.54 and 1.25, respectively. The bimolecular rate constant for the Ev∘−bCD INCLUSION COMPLEX formation is 3.03×103 M−1s−1. These results are supported by the simulation of the experimental cyclic voltammograms. This study also highlights the significance of the proposed electrochemical method as compared to earlier studies on VIOLOGEN-Cyclodextrin systems

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APA: Copy

NAQVI, I.I., SHAZIA, AKBAR, & MOHAMMAD, M.. (2014). ELECTRON TRANSFER REACTIONS ASSOCIATED WITH ETHYL VIOLOGEN-β-CYCLODEXTRIN COMPLEXATION: EQUILIBRIUM AND KINETIC ASPECTS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 11(3), 615-621. SID. https://sid.ir/paper/282752/en

Vancouver: Copy

NAQVI I.I., SHAZIA AKBAR, MOHAMMAD M.. ELECTRON TRANSFER REACTIONS ASSOCIATED WITH ETHYL VIOLOGEN-β-CYCLODEXTRIN COMPLEXATION: EQUILIBRIUM AND KINETIC ASPECTS. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2014;11(3):615-621. Available from: https://sid.ir/paper/282752/en

IEEE: Copy

I.I. NAQVI, AKBAR SHAZIA, and M. MOHAMMAD, “ELECTRON TRANSFER REACTIONS ASSOCIATED WITH ETHYL VIOLOGEN-β-CYCLODEXTRIN COMPLEXATION: EQUILIBRIUM AND KINETIC ASPECTS,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 11, no. 3, pp. 615–621, 2014, [Online]. Available: https://sid.ir/paper/282752/en

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