LIGHT-INDUCED DEHYDROGENATION OF 5-ACETYL-2-METHOXYDIHYDROPYRIMIDINES

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MEMARIAN HAMID R.; REZAIE FAHIMEH

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Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:621 | Volume:10 | Issue:5 Page(s): 857-861

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Information Journal Paper

Title

LIGHT-INDUCED DEHYDROGENATION OF 5-ACETYL-2-METHOXYDIHYDROPYRIMIDINES

Author(s)

MEMARIAN HAMID R. | REZAIE FAHIMEH | Issue Writer Certificate

Keywords

DIHYDROPYRIMIDINES

PHOTO-DEHYDROGENATION

SUBSTITUENT EFFECT

Abstract

Tautomeric mixtures of 4-aryl substituted 5-acetyl-2-methoxyDIHYDROPYRIMIDINES undergo oxidation by exposing to the UV-light under formation of sole pyrimidines. The nature of the 4-substitution and solvent, and the ratio of tautomeric mixtures affect the rate of reaction. A proposed electron transfer-induced PHOTO-DEHYDROGENATION supports the obtained results in this study.

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