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Title

IRON (III) HETERO-LIGAND COMPLEXES CONTAINING 1, 10-PHENANTHROLINE DERIVATIVES, CHLORIDE AND DIMETHYL SULFOXIDE: SYNTHESIS, CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION AND LUMINESCENT PROPERTIES

Pages

  751-761

Abstract

 [Fe(Me-phen)Cl4][Me-phen H] (1) and [Fe(Cl-phen)Cl4][Cl-phen H] (2) complexes were prepared from the reactions of FeCl3 6H2O with 5-METHYL-1, 10-PHENANTHROLINE (Me-phen) and 5-CHLORO-1, 10-PHENANTHROLINE (Cl-phen), respectively, in a 0.1 M aqueous solution of HCl. Stepwise addition of DIMETHYL SULFOXIDE to the solution of 1 in methanol results in a mixed ligand complex, [Fe(Me-phen)Cl3(DMSO)] (3). Complex 3 was also prepared by two other methods. The reaction of a methanol solution of [Fe(Me-phen)Cl4][Me-phen H] (1) with [Fe(DMSO)4Cl2][FeCl4] in 1:6 ratio led to3. Complex 3 was also prepared from the reaction of 5-METHYL-1, 10-PHENANTHROLINE with [Fe(DMSO)4Cl2][FeCl4] in 1:1 ratio in methanol. The three complexes were characterized by IR, UV-Vis, 1H NMR and LUMINESCENCE SPECTROSCOPY and their structures were studied by the single-crystal diffraction method. Calculation methods were employed to study the isomerization of (3) in solution.

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    APA: Copy

    AMANI, VAHID, SAFARI, NASSER, & NOTASH, BEHROUZ. (2013). IRON (III) HETERO-LIGAND COMPLEXES CONTAINING 1, 10-PHENANTHROLINE DERIVATIVES, CHLORIDE AND DIMETHYL SULFOXIDE: SYNTHESIS, CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION AND LUMINESCENT PROPERTIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 10(4), 751-761. SID. https://sid.ir/paper/282942/en

    Vancouver: Copy

    AMANI VAHID, SAFARI NASSER, NOTASH BEHROUZ. IRON (III) HETERO-LIGAND COMPLEXES CONTAINING 1, 10-PHENANTHROLINE DERIVATIVES, CHLORIDE AND DIMETHYL SULFOXIDE: SYNTHESIS, CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION AND LUMINESCENT PROPERTIES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2013;10(4):751-761. Available from: https://sid.ir/paper/282942/en

    IEEE: Copy

    VAHID AMANI, NASSER SAFARI, and BEHROUZ NOTASH, “IRON (III) HETERO-LIGAND COMPLEXES CONTAINING 1, 10-PHENANTHROLINE DERIVATIVES, CHLORIDE AND DIMETHYL SULFOXIDE: SYNTHESIS, CHARACTERIZATION, CRYSTAL STRUCTURE DETERMINATION AND LUMINESCENT PROPERTIES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 10, no. 4, pp. 751–761, 2013, [Online]. Available: https://sid.ir/paper/282942/en

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