INFLUENCE OF METHYL GROUP POSITION IN BIPYRIDINE LIGAND ON STRUCTURE AND LUMINESCENCE OF RELATED ZINC (II) NITRATE COMPLEXES

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NASSER OSTAD S.; ABEDI ANITA; AMANI VAHID; KARIMI PARTO; HEYDARNEZHAD SHAHRZAD

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Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2016 | Volume:13 | Issue:8 Page(s): 0-0

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Title

INFLUENCE OF METHYL GROUP POSITION IN BIPYRIDINE LIGAND ON STRUCTURE AND LUMINESCENCE OF RELATED ZINC (II) NITRATE COMPLEXES

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Keywords

CRYSTAL STRUCTURE ZINC (II) COMPLEXES THERMO GRAVIMETRIC BIPYRIDINE DERIVATIVES LUMINESCENCE SPECTROSCOPY

Abstract

Three new zinc (II) complexes of [Zn (6-mbipy)(h2-NO3)2] (1), [Zn (6,6′-dmbipy) (h2-NO3)2] (2) and [Zn (5,5′-dmbipy) (h2–NO3) (H2O)2] (NO3).H2O (3) were prepared from the reaction of 6-methyl-2, 2′-bipyridine (6-mbipy), 6,6′-dimethyl-2, 2′-bipyridine (6, 6′-dmbipy) and 5, 5′-dimethyl-2, 2′-bipyridine (5, 5′-dmbipy) with Zn(NO3)2.4H2O in methanol, respectively. These three complexes were thoroughly characterized by elemental analysis, thermal gravimetric analysis, differential thermal analysis, infrared, UV–Vis, 1H NMR and 13C {1H} NMR spectroscopy, and their structures have all been determined by the single-crystal X-ray diffraction. The luminescence spectra of the title complexes show that the intensity of their emission bands is stronger than the bands for the free ligands.

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APA: Copy

NASSER OSTAD, S., ABEDI, ANITA, AMANI, VAHID, KARIMI, PARTO, & HEYDARNEZHAD, SHAHRZAD. (2016). INFLUENCE OF METHYL GROUP POSITION IN BIPYRIDINE LIGAND ON STRUCTURE AND LUMINESCENCE OF RELATED ZINC (II) NITRATE COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 13(8), 0-0. SID. https://sid.ir/paper/283191/en

Vancouver: Copy

NASSER OSTAD S., ABEDI ANITA, AMANI VAHID, KARIMI PARTO, HEYDARNEZHAD SHAHRZAD. INFLUENCE OF METHYL GROUP POSITION IN BIPYRIDINE LIGAND ON STRUCTURE AND LUMINESCENCE OF RELATED ZINC (II) NITRATE COMPLEXES. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2016;13(8):0-0. Available from: https://sid.ir/paper/283191/en

IEEE: Copy

S. NASSER OSTAD, ANITA ABEDI, VAHID AMANI, PARTO KARIMI, and SHAHRZAD HEYDARNEZHAD, “INFLUENCE OF METHYL GROUP POSITION IN BIPYRIDINE LIGAND ON STRUCTURE AND LUMINESCENCE OF RELATED ZINC (II) NITRATE COMPLEXES,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 13, no. 8, pp. 0–0, 2016, [Online]. Available: https://sid.ir/paper/283191/en

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