مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

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Information Journal Paper

Title

DESIGN, SYNTHESIS, AND CHARACTERIZATION OF TPA-THIOPHENE-BASED AMIDE OR IMINE FUNCTIONALIZED MOLECULE FOR POTENTIAL OPTOELECTRONIC DEVICES

Pages

  1-9

Abstract

 New sets of molecules containing tri-phenyl-amine (TPA) core and thiophene unit with AMIDE and IMINE functional groups are designed, synthesized, characterized, and compared. These are solution processable small molecules with high mobility. The newly designed molecules have better solubility due to the C=N (imine) and CONH2 (amide) moiety as compared to the established molecules with CH=CH (methine) for optoelectronic applications. They have an optimal energy band gap, which indicates their potential utility in a variety of optoelectronic applications. These molecules also show efficient intermolecular charge transfer mechanisms similar to conventional organic semiconducting molecules as evidenced by optical measurements. Density functional theory simulation results show that the localization of the frontier highest occupied molecular orbital is around the TPA core for molecules coupled with IMINE and AMIDE, and is reasonably stable.

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    Cite

    APA: Copy

    SARSWAT, PRASHANT K., SATHYAPALAN, AMARCHAND, ZHU, YAKUN, & FREE, MICHAEL L.. (2013). DESIGN, SYNTHESIS, AND CHARACTERIZATION OF TPA-THIOPHENE-BASED AMIDE OR IMINE FUNCTIONALIZED MOLECULE FOR POTENTIAL OPTOELECTRONIC DEVICES. JOURNAL OF THEORETICAL AND APPLIED PHYSICS (IRANIAN PHYSICAL JOURNAL), 7(7), 1-9. SID. https://sid.ir/paper/318723/en

    Vancouver: Copy

    SARSWAT PRASHANT K., SATHYAPALAN AMARCHAND, ZHU YAKUN, FREE MICHAEL L.. DESIGN, SYNTHESIS, AND CHARACTERIZATION OF TPA-THIOPHENE-BASED AMIDE OR IMINE FUNCTIONALIZED MOLECULE FOR POTENTIAL OPTOELECTRONIC DEVICES. JOURNAL OF THEORETICAL AND APPLIED PHYSICS (IRANIAN PHYSICAL JOURNAL)[Internet]. 2013;7(7):1-9. Available from: https://sid.ir/paper/318723/en

    IEEE: Copy

    PRASHANT K. SARSWAT, AMARCHAND SATHYAPALAN, YAKUN ZHU, and MICHAEL L. FREE, “DESIGN, SYNTHESIS, AND CHARACTERIZATION OF TPA-THIOPHENE-BASED AMIDE OR IMINE FUNCTIONALIZED MOLECULE FOR POTENTIAL OPTOELECTRONIC DEVICES,” JOURNAL OF THEORETICAL AND APPLIED PHYSICS (IRANIAN PHYSICAL JOURNAL), vol. 7, no. 7, pp. 1–9, 2013, [Online]. Available: https://sid.ir/paper/318723/en

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