Synthesis of 1, 4-disubstituted 1, 2, 3-triazoles Catalyzed byEggshell-supported-Cu(I) Metformin Complex as aHeterogeneous Catalyst in Water

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BAKHERAD MOHAMMAD; Doosti Raheleh; Qasemifar Zeynab

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Journal: Journal of Applied Chemical Research Year:2020 | Volume:14 | Issue:1 Page(s): 8-20

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Title

Synthesis of 1, 4-disubstituted 1, 2, 3-triazoles Catalyzed byEggshell-supported-Cu(I) Metformin Complex as aHeterogeneous Catalyst in Water

Author(s)

BAKHERAD MOHAMMAD | Doosti Raheleh | Qasemifar Zeynab | Issue Writer Certificate

Keywords

3-Triazole

Eggshell-supported-Cu(I) metformin

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Abstract

An efficient and eco-friendly method has been developed for the synthesis of 1, 4-disubstituted 1, 2, 3-Triazoles using the eggshell-supported-Cu(I) metformin complexas a natural and heterogeneous catalyst. The catalyst prepared is characterized by FT-IR spectroscopy, SEM, and ICP techniques. Terminal alkynes were successfully reacted with alkyl chloride and sodium azide in the presence of CuI immobilized on eggshell in water at room temperature. This method offers many advantages such as short reaction times, low cost, use of a reusable catalyst, and simple purification procedures. Moreover, the catalyst could be recovered and recycled four times.

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APA: Copy

BAKHERAD, MOHAMMAD, Doosti, Raheleh, & Qasemifar, Zeynab. (2020). Synthesis of 1, 4-disubstituted 1, 2, 3-triazoles Catalyzed byEggshell-supported-Cu(I) Metformin Complex as aHeterogeneous Catalyst in Water. JOURNAL OF APPLIED CHEMICAL RESEARCH (JACR), 14(1), 8-20. SID. https://sid.ir/paper/323151/en

Vancouver: Copy

BAKHERAD MOHAMMAD, Doosti Raheleh, Qasemifar Zeynab. Synthesis of 1, 4-disubstituted 1, 2, 3-triazoles Catalyzed byEggshell-supported-Cu(I) Metformin Complex as aHeterogeneous Catalyst in Water. JOURNAL OF APPLIED CHEMICAL RESEARCH (JACR)[Internet]. 2020;14(1):8-20. Available from: https://sid.ir/paper/323151/en

IEEE: Copy

MOHAMMAD BAKHERAD, Raheleh Doosti, and Zeynab Qasemifar, “Synthesis of 1, 4-disubstituted 1, 2, 3-triazoles Catalyzed byEggshell-supported-Cu(I) Metformin Complex as aHeterogeneous Catalyst in Water,” JOURNAL OF APPLIED CHEMICAL RESEARCH (JACR), vol. 14, no. 1, pp. 8–20, 2020, [Online]. Available: https://sid.ir/paper/323151/en

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