CRYSTAL STRUCTURE OF [AQUA (2, 2'-BIPYRIDINE) (6-CARBOXYPYRIDINE-2-CARBOXYLATO] COPPER (II) NITRATE MONOHYDRATE COMPLEX AT 150 K

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SOLEIMANNEJAD J.; AGHABOZORG H.; ATTAR GHARAMALEKI J.

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Journal: Iranian Journal of Crystallography and Mineralogy Year:2011 | Volume:19 | Issue:2 Page(s): 35-40

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Title

CRYSTAL STRUCTURE OF [AQUA (2, 2'-BIPYRIDINE) (6-CARBOXYPYRIDINE-2-CARBOXYLATO] COPPER (II) NITRATE MONOHYDRATE COMPLEX AT 150 K

Author(s)

SOLEIMANNEJAD J. | AGHABOZORG H. | ATTAR GHARAMALEKI J. | Issue Writer Certificate

Keywords

CU (II) COMPLEXQ2

CRYSTAL STRUCTUREQ2

PYRIDINE-2Q2

6-DICARBOXYLIC ACIDQ2

2Q2

2'-BIPYRIDINEQ2

HYDROGEN BONDINGQ2

π–π AND C=O...π STACKING INTERACTIONSQ2

Abstract

The reaction of copper (II) nitrate with 2/fa?page=1&sort=1&ftyp=all&fgrp=all&fyrs=all" target="_blank"> PYRIDINE-2, 6-DICARBOXYLIC ACID, (pydcH2) and 2, 2' -bipyridine (2, 2' -bipy) led to the formation of the title compound, [Cu (C7H4NO4) (C10H8N2) (H2O)] NO3.H2O, or [Cu (pydcH) (2, 2' -bipy) (H2O)] NO3.H2O. The crystal system of the complex is triclinic with space group P and two molecules per unit cell. The unit cell parameters are: a=7.0438 (6) A, b=11.3215 (10) A, c=12.9148 (9) A, a=107.498 (4)o, b=94.557 (5)o and g=104.325 (5)o. The final R value was 0.03 for 3601 observed reflections. The cationic complex features six-coordinate CuII with a distorted octahedral geometry with a significantly longer Cu1—O4 bond [2.5491 (16) A]. Considerable C=O···p stacking interactions between the C=O groups with distance of 3.498 (2) A are observed.In addition, d istinct intermolecular O—H ··· O and N—H ··· O hydrogen bonds lead to the formation of R22 (12) and C22 (12) graph sets motifs. In the CRYSTAL STRUCTURE, a wide range of non-covalent interactions consisting of HYDROGEN BONDING (O—H···O, O—H···N and C—H···O), p–p [centroid–centroid distances of 3.5193 (13) A and 3.6876 (13) A] and C=O···p stacking interactions connect the various components into a supramolecular structure.

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APA: Copy

SOLEIMANNEJAD, J., AGHABOZORG, H., & ATTAR GHARAMALEKI, J.. (2011). CRYSTAL STRUCTURE OF [AQUA (2, 2'-BIPYRIDINE) (6-CARBOXYPYRIDINE-2-CARBOXYLATO] COPPER (II) NITRATE MONOHYDRATE COMPLEX AT 150 K. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, 19(2), 35-40. SID. https://sid.ir/paper/365807/en

Vancouver: Copy

SOLEIMANNEJAD J., AGHABOZORG H., ATTAR GHARAMALEKI J.. CRYSTAL STRUCTURE OF [AQUA (2, 2'-BIPYRIDINE) (6-CARBOXYPYRIDINE-2-CARBOXYLATO] COPPER (II) NITRATE MONOHYDRATE COMPLEX AT 150 K. IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY[Internet]. 2011;19(2):35-40. Available from: https://sid.ir/paper/365807/en

IEEE: Copy

J. SOLEIMANNEJAD, H. AGHABOZORG, and J. ATTAR GHARAMALEKI, “CRYSTAL STRUCTURE OF [AQUA (2, 2'-BIPYRIDINE) (6-CARBOXYPYRIDINE-2-CARBOXYLATO] COPPER (II) NITRATE MONOHYDRATE COMPLEX AT 150 K,” IRANIAN JOURNAL OF CRYSTALLOGRAPHY AND MINERALOGY, vol. 19, no. 2, pp. 35–40, 2011, [Online]. Available: https://sid.ir/paper/365807/en

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