Coordination Chemistry, Spectral, and Structural Characterizations of Mercury (II) Complexes with a New Phosphorus Ylide and Confirmation Ylide Reactive Site Toward Interaction with Metal Atom by Computational Methods

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

Dadras Alireza; Ebrahimnezhad Shahla; Pourmirza Mahsa; RAMEZANI ALI; Soldoozi Ali

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Journal Paper

Paper Information

Journal: Nashrieh Shimi va Mohandesi Shimi Iran Year:2019 | Volume:38 | Issue:2 (92) Page(s): 153-164

Download Full-Text

Persian Verion

View:

440

Download:

Cites:

Information Journal Paper

Title

Coordination Chemistry, Spectral, and Structural Characterizations of Mercury (II) Complexes with a New Phosphorus Ylide and Confirmation Ylide Reactive Site Toward Interaction with Metal Atom by Computational Methods

Author(s)

Keywords

Coordination chemistryQ1

Phosphorus ylide complexesQ1

Hg (II) binuclear complexesQ1

Tri-p-tolylphosphaneQ1

Transition metal complexesQ1

Abstract

The reaction of 2-bromo-1-(3-nitrophenyl) ethan-1-one with (Tri-p-tolylphosphane) in acetone as solvent was led to effective ylide of 1-(3-nitrophenyl)-2-(tri-p-tolyl-λ 5-phosphanylidene) ethan-1-one (NTPPY) (1). Then binuclear complexes of the type [HgX2 (ptolyl)3PCHCOC6H4NO2)] (X = Cl, Br and I), were prepared by the reaction of title ylide with mercury (II) halides in equimolar ratios, using dry methanol as solvent. The final products were characterized by IR, 1H, 13C, 31P NMR spectroscopic methods. The solid-state structure of (1) was established by X-ray crystallography analysis. Computational studies at DFT (B3LYP/6-31G*) level of theory were used to confirm ylide reactive site.

Cites

No record.

References

No record.

Cite

APA: Copy

Dadras, Alireza, Ebrahimnezhad, Shahla, Pourmirza, Mahsa, RAMEZANI, ALI, & Soldoozi, Ali. (2019). Coordination Chemistry, Spectral, and Structural Characterizations of Mercury (II) Complexes with a New Phosphorus Ylide and Confirmation Ylide Reactive Site Toward Interaction with Metal Atom by Computational Methods. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 38(2 (92) ), 153-164. SID. https://sid.ir/paper/408522/en

Vancouver: Copy

Dadras Alireza, Ebrahimnezhad Shahla, Pourmirza Mahsa, RAMEZANI ALI, Soldoozi Ali. Coordination Chemistry, Spectral, and Structural Characterizations of Mercury (II) Complexes with a New Phosphorus Ylide and Confirmation Ylide Reactive Site Toward Interaction with Metal Atom by Computational Methods. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2019;38(2 (92) ):153-164. Available from: https://sid.ir/paper/408522/en

IEEE: Copy

Alireza Dadras, Shahla Ebrahimnezhad, Mahsa Pourmirza, ALI RAMEZANI, and Ali Soldoozi, “Coordination Chemistry, Spectral, and Structural Characterizations of Mercury (II) Complexes with a New Phosphorus Ylide and Confirmation Ylide Reactive Site Toward Interaction with Metal Atom by Computational Methods,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 38, no. 2 (92) , pp. 153–164, 2019, [Online]. Available: https://sid.ir/paper/408522/en

Related Journal Papers