A REINVESTIGATION OF NITRATION OF PHENOLS WITH METAL NITRATES UNDER NON-AQUEOUS AND APROTIC CONDITIONS

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FIROUZABADI H.; IRANPOUR N.; ZOLFIGOL M.A.

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Journal Paper

Paper Information

Journal: IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING Year:1997 | Volume:16 | Issue:2 Page(s): 48-58

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Title

A REINVESTIGATION OF NITRATION OF PHENOLS WITH METAL NITRATES UNDER NON-AQUEOUS AND APROTIC CONDITIONS

Author(s)

FIROUZABADI H. | IRANPOUR N. | ZOLFIGOL M.A.

Keywords

NITRATION; METAL NITRATES; MONONITRATION; DINITRATION; PHENOL

Abstract

Nitration of phenol and various 4-substituted phenols with Cu(NO3)(2) . 3H(2)O, Cu(NO3)(2) . 3H(2)O/SiO2, Fe(NO3)(3) . 9H(2)O and Cr(NO3)(3). 9H(2)O in different anhydrous organic solvents are investigated High selectivity ratio of para vs ortho isomers has been observed Mono-and dinitro compounds from phenol and 4-substituted phenols by choosing the proper solvents and reaction conditions, are also obtained with high selectivity in excellent yields. Rate enhancement for mononitration of phenols in the presence of LiClO4 with Cu(NO3)(2). 3H(2)O is observed.

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APA: Copy

FIROUZABADI, H., IRANPOUR, N., & ZOLFIGOL, M.A.. (1997). A REINVESTIGATION OF NITRATION OF PHENOLS WITH METAL NITRATES UNDER NON-AQUEOUS AND APROTIC CONDITIONS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 16(2), 48-58. SID. https://sid.ir/paper/529242/en

Vancouver: Copy

FIROUZABADI H., IRANPOUR N., ZOLFIGOL M.A.. A REINVESTIGATION OF NITRATION OF PHENOLS WITH METAL NITRATES UNDER NON-AQUEOUS AND APROTIC CONDITIONS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 1997;16(2):48-58. Available from: https://sid.ir/paper/529242/en

IEEE: Copy

H. FIROUZABADI, N. IRANPOUR, and M.A. ZOLFIGOL, “A REINVESTIGATION OF NITRATION OF PHENOLS WITH METAL NITRATES UNDER NON-AQUEOUS AND APROTIC CONDITIONS ,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 16, no. 2, pp. 48–58, 1997, [Online]. Available: https://sid.ir/paper/529242/en

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