SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS

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SESSLER J.

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Journal Paper

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Journal: Iranian Journal of Chemistry and Chemical Engineering Year:1994 | Volume:13 | Issue:2 Page(s): 83-90

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Title

SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS

Author(s)

SESSLER J.

Keywords

COPPER(II); EXPANDED PORPHYRINS; COMPLEXES

Abstract

The synthesis and characterization of some new binuclear copper(II) complexes, based on the use of large, pyrole- containing macrocycles, the so called ""expanded porphyrins"", [Cu-2(macrycycle)](+4) is described. Electron Spin Resonance (ESR) studies indicate a weak ""half-field line"" which is characteristic of the Cu(II)-Cu(II) dimer, is observed at about 1600G. The observation of this band strongly suggests that the hyperfine structure arises from a spin triplet species.

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APA: Copy

SESSLER, J.. (1994). SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 13(2), 83-90. SID. https://sid.ir/paper/532592/en

Vancouver: Copy

SESSLER J.. SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS . IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 1994;13(2):83-90. Available from: https://sid.ir/paper/532592/en

IEEE: Copy

J. SESSLER, “SYNTHESIS OF BINUCLEAR COPPER(II) COMPLEXES WITH EXPANDED PORPHYRINS ,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 13, no. 2, pp. 83–90, 1994, [Online]. Available: https://sid.ir/paper/532592/en

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