AN INVESTIGATION OF Z-IN DISTORTION IN MONONUCLEAR CU(II) COMPLEX WITH TERPYRIDINE LIGANDS, [CU(TERPY)2](PF6)2

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SARAVANI H.; REZVANI A.R.; HADADZADEH H.; SAFARI N.

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Journal Paper

Paper Information

Journal: Iranian Journal of Chemistry and Chemical Engineering Year:2007 | Volume:26 | Issue:3 Page(s): 103-110

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Title

AN INVESTIGATION OF Z-IN DISTORTION IN MONONUCLEAR CU(II) COMPLEX WITH TERPYRIDINE LIGANDS, [CU(TERPY)2](PF6)2

Author(s)

SARAVANI H. | REZVANI A.R. | HADADZADEH H. | SAFARI N. | Issue Writer Certificate

Keywords

CU(II) COMPLEX

TERPYRIDINE

Z-IN DISTORTION

CRYSTAL STRUCTURE

MLCT

EVANS METHOD

Abstract

The first CRYSTAL STRUCTURE of [Cu (terpy)2] (PF6)2 , where terpy=2,2':6',2"-terpyridine is reported. Green crystals of [Cu (terpy)2] (PF6)2 were grown by ether diffusion into an acetonitrile solution of the complex. CRYSTAL STRUCTURE of this complex is tetragonal (space group: p`4 21c) with a=8.8916 (3), c=20.0214 (13) A, and z=2. The structure was refined by using 1828 independent reflections with I>2s(I) to a R factor of 0.0809. The terpy ligands are tridentate and linked to the Cu (II) via three N atoms. The CuN6 entities have compressed octahedral geometry with the shortest Cu-N bonds that form the axial positions. This complex represents Z-IN DISTORTION at 293K and has a D2d point group. The effective magnetic moment (meff) of [Cu (terpy)2] (PF6)2 was measured to be 1.95BM by EVANS METHOD. Cyclic voltammetry experiment of the complex shows that the Cu (II/I) couple is quasi-reversible.

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APA: Copy

SARAVANI, H., REZVANI, A.R., HADADZADEH, H., & SAFARI, N.. (2007). AN INVESTIGATION OF Z-IN DISTORTION IN MONONUCLEAR CU(II) COMPLEX WITH TERPYRIDINE LIGANDS, [CU(TERPY)₂](PF₆)_{2. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), 26(3), 103-110. SID. https://sid.ir/paper/558892/en}

Vancouver: Copy

SARAVANI H., REZVANI A.R., HADADZADEH H., SAFARI N.. AN INVESTIGATION OF Z-IN DISTORTION IN MONONUCLEAR CU(II) COMPLEX WITH TERPYRIDINE LIGANDS, [CU(TERPY)₂](PF₆)_{2. IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE)[Internet]. 2007;26(3):103-110. Available from: https://sid.ir/paper/558892/en}

IEEE: Copy

H. SARAVANI, A.R. REZVANI, H. HADADZADEH, and N. SAFARI, “AN INVESTIGATION OF Z-IN DISTORTION IN MONONUCLEAR CU(II) COMPLEX WITH TERPYRIDINE LIGANDS, [CU(TERPY)₂](PF₆)_{2,” IRANIAN JOURNAL OF CHEMISTRY AND CHEMICAL ENGINEERING (IJCCE), vol. 26, no. 3, pp. 103–110, 2007, [Online]. Available: https://sid.ir/paper/558892/en}

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