SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES USING THE MULTICOMPONENT REACTION OF TRIPHENYLPHOSPHIN IN WATER

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AFSHARI SHARIFABAD SAEID; HOSSAINI ZINATOSSADAT

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Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES USING THE MULTICOMPONENT REACTION OF TRIPHENYLPHOSPHIN IN WATER

Author(s)

AFSHARI SHARIFABAD SAEID | HOSSAINI ZINATOSSADAT

Keywords

Not Registered.

Abstract

ONE OF THE POWERFUL TOOLS USED TO JOIN ECONOMIC ASPECTS WITH THE ENVIRONMENTAL CONCERNS IS PERFORMING ORGANIC REACTIONS IN WATER; THIS STRATEGY CONSISTS OF TWO OR MORE SYNTHETIC STEPS, WHICH ARE CARRIED OUT IN WATER AS A CHEAP, NONTOXIC, ENVIRONMENTALLY FRIENDLY SOLVENT, IN A ONE-STEP REACTION, WITHOUT ISOLATION OF ANY INTERMEDIATE THUS REDUCING TIME, SAVING MONEY, ENERGY AND RAW MATERIALS. MULTICOMPONENT REACTIONS (MCRS), WITH THREE OR MORE REACTANTS COMBINE IN A ONE-POT PROCEDURE TO GIVE A SINGLE PRODUCT, HAVE BECOME INCREASINGLY POPULAR DURING THE LAST DECADE.MCRS ARE PERFECTLY SUITED FOR COMBINATORIAL LIBRARY SYNTHESIS, AND THUS ARE FINDING INCREASED USE IN THE DISCOVERY PROCESS FOR NEW DRUGS AND AGROCHEMICALS.HEREIN WE DESCRIBE AN EFFICIENT SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES5 VIA THE REACTION OF TRIPHENYLPHOSPHINE1, DIALKYL ACETYLENEDICARBOXYLAT 2, 3, AND PRIMARY AMINES 4 IN WATER AS THE SOLVENT AT 80OC IN GOOD YIELDS WITHOUT USING ANY CATALYST AND LOW TIME.

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APA: Copy

AFSHARI SHARIFABAD, SAEID, & HOSSAINI, ZINATOSSADAT. (2012). SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES USING THE MULTICOMPONENT REACTION OF TRIPHENYLPHOSPHIN IN WATER. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909481/en

Vancouver: Copy

AFSHARI SHARIFABAD SAEID, HOSSAINI ZINATOSSADAT. SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES USING THE MULTICOMPONENT REACTION OF TRIPHENYLPHOSPHIN IN WATER. 2012. Available from: https://sid.ir/paper/909481/en

IEEE: Copy

SAEID AFSHARI SHARIFABAD, and ZINATOSSADAT HOSSAINI, “SYNTHESIS OF CYCLOPENTADIENE DERIVATIVES USING THE MULTICOMPONENT REACTION OF TRIPHENYLPHOSPHIN IN WATER,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909481/en

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