SOLVENT-FREE SYNTHESIS OF FUNCTIONALIZED PYRROLES FROM THE MULTICOMPONENT REACTIONS OF PRIMARY AMINES

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KHALILI TILAMI HODA; HOSSAINI ZINATOSSADAT

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Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

SOLVENT-FREE SYNTHESIS OF FUNCTIONALIZED PYRROLES FROM THE MULTICOMPONENT REACTIONS OF PRIMARY AMINES

Author(s)

KHALILI TILAMI HODA | HOSSAINI ZINATOSSADAT

Keywords

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Abstract

THE METHODS OF GREEN CHEMISTRY CONTINUE TO GROW IN IMPORTANCE. ALTERNATIVE PROCESSES HELP TO CONSERVE RESOURCES AND CAN EVEN REDUCE COSTS. THE REPLACEMENT OF CONVENTION SOLVENTS WITH WATER OR SOLVENT-FREE CONDITIONS, WHICH IS HARMLESS TO HEALTH AND IS AVAILABLE IN LARGE QUANTITIES, IS ONE OF THE MOST INTERESTING BASIC APPROACHES ALONG THESE LINES. MULTICOMPONENT REACTIONS (MCRS) HAVE BEEN GENERALLY USED BY SYNTHETIC CHEMISTS AS A BASIC MEANS TO GENERATE MOLECULAR DIVERSITY FROM BIFUNCTIONAL SUBSTRATES THAT REACT REPEATEDLY IN AN INTRAMOLECULAR METHOD. HIGHLY SUBSTITUTED PYRROLE PLAY AN IMPORTANT ROLE IN ORGANIC CHEMISTRY, NOT ONLY AS KEY STRUCTURAL UNITS IN MANY NATURAL PRODUCTS, COMMON SUBUNITS IN PHARMACEUTICALS, FRAGRANCES, AND FLAVORS, BUT ALSO AS USEFUL BUILDING BLOCKS IN SYNTHETIC CHEMISTRY.HEREIN, WE REPORT AN EFFICIENT SYNTHESIS OF FUNCTIONALIZED PYRROLES4 FROM THE REACTION OF PRIMARY AMINES1, ACTIVATED ACETYLENES 2 AND ACTIVATED CARBONYL COMPOUNDS SUCH AS NINHYDRINE 3 UNDER SOLVENT-FREE CONDITIONS AT 50OC IN GOOD YIELD.

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APA: Copy

KHALILI TILAMI, HODA, & HOSSAINI, ZINATOSSADAT. (2012). SOLVENT-FREE SYNTHESIS OF FUNCTIONALIZED PYRROLES FROM THE MULTICOMPONENT REACTIONS OF PRIMARY AMINES. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909482/en

Vancouver: Copy

KHALILI TILAMI HODA, HOSSAINI ZINATOSSADAT. SOLVENT-FREE SYNTHESIS OF FUNCTIONALIZED PYRROLES FROM THE MULTICOMPONENT REACTIONS OF PRIMARY AMINES. 2012. Available from: https://sid.ir/paper/909482/en

IEEE: Copy

HODA KHALILI TILAMI, and ZINATOSSADAT HOSSAINI, “SOLVENT-FREE SYNTHESIS OF FUNCTIONALIZED PYRROLES FROM THE MULTICOMPONENT REACTIONS OF PRIMARY AMINES,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909482/en

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