THREE-COMPONENT REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES AND DIALKYL ACETYLENEDICARBOXYLATES IN THE PRESENCE OF ETHYL TRIFLUOROACETATE: ONE-POT SYNTHESIS OF FUNCTIONALIZED DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2...

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

KHANDAN BARANI KHATEREH; MAGHSOODLOU MALEK TAHER; SHARAKI MEHDI; ELMI SHIRIN

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

Download Full-Text

View:

106

Download:

Information Seminar Paper

Title

THREE-COMPONENT REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES AND DIALKYL ACETYLENEDICARBOXYLATES IN THE PRESENCE OF ETHYL TRIFLUOROACETATE: ONE-POT SYNTHESIS OF FUNCTIONALIZED DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2...

Author(s)

KHANDAN BARANI KHATEREH | MAGHSOODLOU MALEK TAHER | SHARAKI MEHDI | ELMI SHIRIN

Keywords

Not Registered.

Abstract

THE DEVELOPMENT OF NEW AND SIMPLE SYNTHETIC APPROACHES FOR FULLY USED ORGANIC COMPOUNDS FROM READILY AVAILABLE REAGENTS IS ONE OF THE MAJOR AIMS IN ORGANIC SYNTHESIS. THE MULTICOMPONENT REACTIONS (MCRS), BY VIRTUE OF THEIR CONVERGENCE, PRODUCTIVITY, FACILE EXECUTION AND GENERALLY HIGH YIELDS OF PRODUCTS, HAVE ATTRACTED MUCH ATTENTION FROM THE VANTAGE POINT OF SYNTHETIC CHEMISTRY. IN PARTICULAR, ISOCYANIDE-BASED MULTICOMPONENT REACTIONS APPLY TO THE SYNTHESIS OF VARIOUS FURAN AND FURAN DERIVATIVES. WE NOW REPORT THE RESULT OF OUR INVESTIGATIONS FOR THE REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES1 AND DIALKYL ACETYLENEDICARBOXYLATES 2 IN THE PRESENCE OF ETHYL TRIFLUOROACETATE3 IN REFLUXING CH2CL2. THE ONE-POT THREE-COMPONENT CONDENSATION REACTION WAS PROCEEDED AT 38OC AND COMPLETED AFTER 24H TO AFFORD DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2, 5-DIHYDROFURAN-3, 4-DICARBOXYLATE4 IN GOOD ISOLATED YIELDS IN THE ABSENCE OF A CATALYST. THE STRUCTURE OF COMPOUNDS4A-J WAS DEDUCED FROM THEIR IR, 1H NMR, 13C NMR, 19F NMR, MASS SPECTRAL DATA AND ELEMENTAL ANALYSIS. THE PRESENT PROCEDURE HAS THE ADVANTAGE THAT NOT ONLY THE REACTION IS PERFORMED UNDER NEUTRAL CONDITIONS BUT ALSO THE REACTANTS CAN BE MIXED WITHOUT ANY ACTIVATION OR MODIFICATION.

Cites

No record.

References

No record.

Cite

APA: Copy

KHANDAN BARANI, KHATEREH, SHARAKI, MEHDI, & ELMI, SHIRIN. (2012). THREE-COMPONENT REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES AND DIALKYL ACETYLENEDICARBOXYLATES IN THE PRESENCE OF ETHYL TRIFLUOROACETATE: ONE-POT SYNTHESIS OF FUNCTIONALIZED DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2.... IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909500/en

Vancouver: Copy

KHANDAN BARANI KHATEREH, SHARAKI MEHDI, ELMI SHIRIN. THREE-COMPONENT REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES AND DIALKYL ACETYLENEDICARBOXYLATES IN THE PRESENCE OF ETHYL TRIFLUOROACETATE: ONE-POT SYNTHESIS OF FUNCTIONALIZED DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2.... 2012. Available from: https://sid.ir/paper/909500/en

IEEE: Copy

KHATEREH KHANDAN BARANI, MEHDI SHARAKI, and SHIRIN ELMI, “THREE-COMPONENT REACTION BETWEEN ALKYL (ARYL) ISOCYANIDES AND DIALKYL ACETYLENEDICARBOXYLATES IN THE PRESENCE OF ETHYL TRIFLUOROACETATE: ONE-POT SYNTHESIS OF FUNCTIONALIZED DIALKYL 5- [ALKYL (ARYL) IMINO] -2-ETHOXY-2- (TRIFLUOROMETHYL) -2...,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909500/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops