TAUTOMERISM IN 2-KETOMETHYLQUINOLINEAZINES

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LOGHMANI KHOUZANI HOSSEIN; GAWINECKI RYSZARD; MINAEIFAR ALIREZA; MEHRABI HOSSEIN

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Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2012 | Issue:19

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Title

TAUTOMERISM IN 2-KETOMETHYLQUINOLINEAZINES

Author(s)

LOGHMANI KHOUZANI HOSSEIN | GAWINECKI RYSZARD | MINAEIFAR ALIREZA | MEHRABI HOSSEIN

Keywords

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Abstract

AZINES ARE A CLASS OF COMPOUNDS THAT UNDERGOES A WIDE VARIETY OF CHEMICAL PROCESSES AND HAVE INTERESTING CHEMICAL PROPERTIES [1]. NEW AZINES STUDIED IN THE PRESENT PAPER HAVE BEEN SYNTHESIS IN THREE STEPS. AT FIRST, A SERIES OF 2-KETOMETHYLQUINOLINES HAVE BEEN PREPARED USING THE LITERATURE METHODS [2]. TAUTOMERISM FOR THIS GROUP OF COMPOUNDS WAS ALSO REPORTED BY SEVERAL INVESTIGATORS [3]. IN THE NEXT STEP 2-KETOMETHYLQUINOLINES IN REACTION WITH HYDRAZINE IN ETHANOL SOLUTION AND A DROP OF ACETIC ACID AS A CATALYST WAS CONVERTED TO 2-KETOMETHYLQUINOLINEHYDRAZONES IN GOOD TO HIGH YIELDS. STRUCTURE OF ALL COMPOUNDS HAS BEEN ELUCIDATED USING SPECTROSCOPIC METHODS AND ELEMENTAL ANALYSIS. OUR STUDY SHOW THAT IN CHLOROFORM SOLUTION GENERALLY TWO TAUTOMERIC FORMS ARE IN EQUILIBRIUM. HOWEVER, IN SOME CASES ONLY ONE TAUTOMER WAS DETECTED.

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APA: Copy

LOGHMANI KHOUZANI, HOSSEIN, GAWINECKI, RYSZARD, MINAEIFAR, ALIREZA, & MEHRABI, HOSSEIN. (2012). TAUTOMERISM IN 2-KETOMETHYLQUINOLINEAZINES. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/909514/en

Vancouver: Copy

LOGHMANI KHOUZANI HOSSEIN, GAWINECKI RYSZARD, MINAEIFAR ALIREZA, MEHRABI HOSSEIN. TAUTOMERISM IN 2-KETOMETHYLQUINOLINEAZINES. 2012. Available from: https://sid.ir/paper/909514/en

IEEE: Copy

HOSSEIN LOGHMANI KHOUZANI, RYSZARD GAWINECKI, ALIREZA MINAEIFAR, and HOSSEIN MEHRABI, “TAUTOMERISM IN 2-KETOMETHYLQUINOLINEAZINES,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2012, [Online]. Available: https://sid.ir/paper/909514/en

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