TOPOLOGY STUDY OF THE ZN (ADC)2(HTEA)2 METAL ORGANIC FRAMEWORK SYNTHESIS AND CHARACTERIZATION OF A TWO-FOLD DIA METAL ORGANIC FRAMEWORK

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GHARIB MANIYA; ABBASI ALIREZA; GERANMAYEH SHOKOOFEH

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Seminar: IRANIAN INORGANIC CHEMISTRY CONFERENCE
Year:2014 | Issue:16

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Title

TOPOLOGY STUDY OF THE ZN (ADC)2(HTEA)2 METAL ORGANIC FRAMEWORK SYNTHESIS AND CHARACTERIZATION OF A TWO-FOLD DIA METAL ORGANIC FRAMEWORK

Author(s)

GHARIB MANIYA | ABBASI ALIREZA | GERANMAYEH SHOKOOFEH | Issue Writer Certificate

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Abstract

IN THE PAST DECADE, THE DESIGN AND SYNTHESIS OF FUNCTIONAL MOLECULE ANALOGUES BY THE SELFASSEMBLY OF METAL-CONNECTING POINTS AND ORGANIC LINKERS UNDER CONTROLLED REACTION CONDITIONS HAS ATTRACTED A GREAT DEAL OF ATTENTION AMONG THE INORGANIC, MATERIALS, AND SUPRAMOLECULAR CHEMISTRY COMMUNITIES. AS A RESULT OF THESE EFFORTS, THE STUDIES ON THE SYNTHESES OF METAL-ORGANIC FRAMEWORKS (MOFS) HAVE UNDERGONE TREMENDOUS DEVELOPMENT .IN THIS STUDY WE INVESTIGATE THE TOPOLOGY OF THE ZN(ADC)2.(HTEA)2,(ADC=ACETYLENEDICARBOXYLICACID , HTEA= TRIETHYLAMINE) STRUCTURE. A BETTER INSIGHT INTO THE NATURE OF THIS ARCHITECTURE CAN BE ACHIEVED BY TOPOLOGICAL ANALYSIS. THE STRUCTURE HAS BEEN CHARACTERIZED BY POWDER X-RAY DIFFRACTION.TETRAHEDRAL SBU IN THIS ZN(ADC)2.(HTEA)2 COMPLEX IS LINKED INTO DIAMOND NETWORKS. FROM TOPOLOGICAL POINT OF VIEW, ONE CAN CONSIDER ZN(CO2)4 UNIT AS TETRAHEDRAL INORGANIC SBU LIKED THROUGH ACETYLENE SPACER TO FORM TWO-FOLD INTERPENETRATEDDIAFRAMEWORK (FIG.1). EACH SINGLE NET FORM PORES WITH SBU…SBU SEPARATION OF 13.3´17.9 Å2 (FIG.2). ALTHOUGH THE FACT THAT SBU HAVE THE FLEXIBILITY TO BE OF ANY CONE TIVITY, SIZE AND STEREOCHEMISTRY PROMISES THE DESIGN AND SYNTHESIS OF WIDE DIVERSITY OF FUNCTIONAL MOFS.

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APA: Copy

GHARIB, MANIYA, ABBASI, ALIREZA, & GERANMAYEH, SHOKOOFEH. (2014). TOPOLOGY STUDY OF THE ZN (ADC)₂(HTEA)₂ METAL ORGANIC FRAMEWORK SYNTHESIS AND CHARACTERIZATION OF A TWO-FOLD DIA METAL ORGANIC FRAMEWORK. IRANIAN INORGANIC CHEMISTRY CONFERENCE. SID. https://sid.ir/paper/912738/en

Vancouver: Copy

GHARIB MANIYA, ABBASI ALIREZA, GERANMAYEH SHOKOOFEH. TOPOLOGY STUDY OF THE ZN (ADC)₂(HTEA)₂ METAL ORGANIC FRAMEWORK SYNTHESIS AND CHARACTERIZATION OF A TWO-FOLD DIA METAL ORGANIC FRAMEWORK. 2014. Available from: https://sid.ir/paper/912738/en

IEEE: Copy

MANIYA GHARIB, ALIREZA ABBASI, and SHOKOOFEH GERANMAYEH, “TOPOLOGY STUDY OF THE ZN (ADC)₂(HTEA)₂ METAL ORGANIC FRAMEWORK SYNTHESIS AND CHARACTERIZATION OF A TWO-FOLD DIA METAL ORGANIC FRAMEWORK,” presented at the IRANIAN INORGANIC CHEMISTRY CONFERENCE. 2014, [Online]. Available: https://sid.ir/paper/912738/en

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