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Title

SYNTHESIS AND CHARACTERIZATION OF METAL ORGANIC FRAMEWORK BASED PORPHYRIN

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Abstract

 MOFS ARE HIGHLY ORDERED CRYSTALLINE COORDINATION POLYMERS WITH WELL-DEFINED POROUS NETWORKS. AS A RESULT OF THEIR POTENTIAL APPLICATIONS ASSOCIATED WITH THE PRESENCE OF PORES AND CAVITIES, SUCH MATERIALS HAVE BEEN EXAMINED FOR STORAGE, SEPARATIONS, SENSORS, SIZE AND SHAPE-SELECTIVE CATALYSIS, MOLECULAR RECOGNITION AND NANOSCALE REACTORS. METALLOPORPHYRINS ARE VERY STABLE P-CONJUGATED MACROCYCLIC MOLECULES FORMING A DIVERSE CLASS OF MULTIFUNCTIONAL MATERIALS, WHICH EXHIBIT INTERESTING AND USEFUL CATALYTIC, OPTICAL, ELECTRONIC AND BIOLOGICAL PROPERTIES. METALLOPORPHYRIN MOLECULES ARE EXCELLENT CANDIDATES TO ACT AS COMPONENTS OF MOLECULAR BUILDING BLOCKS FOR THE CONSTRUCTION OF MOFS BECAUSE OF THE HUGE VARIETY OF AVAILABLE DERIVATIVES INCORPORATING DIFFERENT CENTRE-COORDINATED METALS AND VARIOUS FUNCTIONAL GROUP SUBSTITUENTS IN THE PERIPHERY OF THE MOLECULE, THEREBY ALLOWING FINE CONTROL OF THE LINKAGE MOTIF [1,2].THE PROCEDURE INVOLVED SPREADING A SOLUTION OF THE MOLECULAR BUILDING UNITS COMPRISING 5,10,15,20-TETRAKIS(4-CARBOXYPHENYL) PORPHYRIN (0.1 G, 0.03MMOL) IN DMF (9.5 ML) AND CU(NO3)2.3H2O (0.0305 G, 0.03 MMOL) IN ETOH (3.2 ML), THEN THE TWO SOLUTIONS WERE ADDED TOGETHER. THE PRODUCT WAS OBTAINED UNDER HYDROTHERMAL CONDITIONSFOR 24 H. THE PRODUCT WAS FILTERED AND WASHED WITH DMF.

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    APA: Copy

    SHARIATYNIA, SAMANEH, ZARGARI, SOLMAZ, & RAHIMI, RAHMATOLLAH. (2014). SYNTHESIS AND CHARACTERIZATION OF METAL ORGANIC FRAMEWORK BASED PORPHYRIN. IRANIAN INORGANIC CHEMISTRY CONFERENCE. SID. https://sid.ir/paper/912834/en

    Vancouver: Copy

    SHARIATYNIA SAMANEH, ZARGARI SOLMAZ, RAHIMI RAHMATOLLAH. SYNTHESIS AND CHARACTERIZATION OF METAL ORGANIC FRAMEWORK BASED PORPHYRIN. 2014. Available from: https://sid.ir/paper/912834/en

    IEEE: Copy

    SAMANEH SHARIATYNIA, SOLMAZ ZARGARI, and RAHMATOLLAH RAHIMI, “SYNTHESIS AND CHARACTERIZATION OF METAL ORGANIC FRAMEWORK BASED PORPHYRIN,” presented at the IRANIAN INORGANIC CHEMISTRY CONFERENCE. 2014, [Online]. Available: https://sid.ir/paper/912834/en

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