HG (II) COMPLEXES OF BIDENTATE PHOSPHINE–PHOSPHONIUM SALTS: SYNTHESIS AND SPECTRAL CHARACTERIZATION

Q: How can I download an article?

To download an article from SID, first log in to the site, search for the article title, and click on the 'Download Article' option.

Q: How can I download an ISI article?

To download an ISI article on SID, enter the keyword or article title in the search bar, view the relevant results, click on the desired article, and select the 'Download Article' option.

Q: How can I access the SID database?

To access the SID database, visit SID.ir, create an account, and log in to access scientific resources.

Q: Is downloading articles from SID free?

Some articles on SID are available for free, while others require payment. Details are specified on the article's page.

SABOUNCHEI SEYYED JAVAD; BERIMAVANDI NEDA

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Seminar Paper

Paper Information

Seminar: IRANIAN INORGANIC CHEMISTRY CONFERENCE
Year:2014 | Issue:16

Download Full-Text

View:

142

Download:

Information Seminar Paper

Title

HG (II) COMPLEXES OF BIDENTATE PHOSPHINE–PHOSPHONIUM SALTS: SYNTHESIS AND SPECTRAL CHARACTERIZATION

Author(s)

SABOUNCHEI SEYYED JAVAD | BERIMAVANDI NEDA | Issue Writer Certificate

Keywords

Not Registered.

Abstract

PHOSPHONIUM SALTS ARE USEFUL INTERMEDIATES IN ORGANIC SYNTHESIS, EXHIBITING VARIETY OF REACTIVITY WHEN COMPARED WITH THE AMMONIUM OR PYRIDINIUM SALTS [1]. DIFFERENT TYPES OF HOMO AND HETEROPOLYNUCLEARYLIDE COMPLEXES OF HG (II), PD (II) AND AU (I) WERE PREPARED USING THE CORRESPONDING PHOSPHONIUM SALTS, BY DEPROTONATION [2]. IN THE FIELD OF CATIONIC POLYMERIZATION, PHOSPHONIUM SALTS SHOWED PROMISE AS LATENT THERMAL- OR PHOTOINITIATORS DUE TO THEIR ABILITY TO FORM THE CORRESPONDING STABLE YLIDES BY RELEASING A PROTON [3-5]. IN 2009 M. EBRAIM ET AL. [6] HAVE REPORTED THE REACTIONS OF PHOSPHONIUM SALT, [PPH2CH2PPH2CH2C(O)PH]BR WITH HG (II) HALIDES IN METHANOL FORMED THE ZWITTERIONIC PRODUCTS. IN 2013 SABOUNCHEI ET AL. [7] REPORTED THE FORMATION OF ZWITTERIONIC P-COORDINATED COMPLEXES OF MERCURY (II) HALIDES WITH PHOSPHINE– PHOSPHONIUM SALTS. IN THIS STUDY WE REPORT THE REACTION OF PHOSPHONIUM SALT [PH2PCH2PPH2CH2C(O)C6H4NO2]BR (L)WITH HG (II) HALIDES IN 1:1 (HGCL2 AND HGBR2) AND 1:2 (HGI2) MOLE RATIO LEADS TO THE ZWITTERIONIC P-COORDINATED COMPLEXES [HGCL2BR(L)] (1), [HGBR3(L)] (2) AND [HGBR2I(L)] (3). CHARACTERIZATION OF THESE COMPOUNDS WAS ALSO PERFORMED BY ELEMENTAL ANALYSIS, IR, 1H, 31P, AND 13C NMR SPECTROSCOPY.

Multimedia

No record.

Cites

No record.

References

No record.

Cite

APA: Copy

SABOUNCHEI, SEYYED JAVAD, & BERIMAVANDI, NEDA. (2014). HG (II) COMPLEXES OF BIDENTATE PHOSPHINE–PHOSPHONIUM SALTS: SYNTHESIS AND SPECTRAL CHARACTERIZATION. IRANIAN INORGANIC CHEMISTRY CONFERENCE. SID. https://sid.ir/paper/912986/en

Vancouver: Copy

SABOUNCHEI SEYYED JAVAD, BERIMAVANDI NEDA. HG (II) COMPLEXES OF BIDENTATE PHOSPHINE–PHOSPHONIUM SALTS: SYNTHESIS AND SPECTRAL CHARACTERIZATION. 2014. Available from: https://sid.ir/paper/912986/en

IEEE: Copy

SEYYED JAVAD SABOUNCHEI, and NEDA BERIMAVANDI, “HG (II) COMPLEXES OF BIDENTATE PHOSPHINE–PHOSPHONIUM SALTS: SYNTHESIS AND SPECTRAL CHARACTERIZATION,” presented at the IRANIAN INORGANIC CHEMISTRY CONFERENCE. 2014, [Online]. Available: https://sid.ir/paper/912986/en

Related Journal Papers

No record.

Related Seminar Papers

No record.

Related Plans

No record.

Recommended Workshops