CUSO4/PYROGALLOL SYSTEM PROMOTED SYNTHESIS OF 1, 2, 3-TRIAZOLES VIA CLICK REACTION

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MIRJALILI B.F.; BAMONIRI A.; ASADI M.

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Seminar Paper

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Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2014 | Issue:22

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Title

CUSO4/PYROGALLOL SYSTEM PROMOTED SYNTHESIS OF 1, 2, 3-TRIAZOLES VIA CLICK REACTION

Author(s)

MIRJALILI B.F. | BAMONIRI A. | ASADI M. | Issue Writer Certificate

Keywords

3-TRIAZOLE

CLICK REACTION

AZIDE

Abstract

1, 2, 3-TRIAZOLES, CLASSIC NITROGEN HETEROCYCLIC COMPOUNDS, ARE AN IMPORTANT CLASS OF MOLECULES, WHICH DISPLAY A BROAD SPECTRUM OF BIOLOGICAL ACTIVITIES. THESE COMPOUNDS ARE ALSO WIDELY EMPLOYED IN VARIOUS FIELDS OF CHEMISTRY, SUCH AS IN THE RESEARCH AND MODULATION OF DRUG CANDIDATES. 1, 2, 3-TRIAZOLE DERIVATIVES HAVE BEEN REPORTED AS ANTIBACTERIAL, ANTIFUNGAL, ANTITUBERCULAR, ANTICANCER, ANTIVIRAL, ANTIHYPERTENSIVE, ANTICHOLINERGIC AND ANTI-INFLAMMATORY AGENTS [1]. THERE IS A VARIETY OF METHODS AVAILABLE IN THE LITERATURE FOR THE PREPARATION OF 1, 2, 3-TRIAZOLES. THE MOST ATTRACTIVE WAY TO PREPARE 1, 2, 3-TRIAZOLES INVOLVES THE THERMAL 1, 3-DIPOLAR CYCLOADDITION OF AZIDES WITH ALKYNES, VIA CLICK REACTION [2]. USUALLY, A MIXTURE OF CUSO4 AND SODIUM ASCORBAT WAS USED FOR IN-SITU PREPARATION OF CU (I) FOR PROMOTION OF THIS REACTION [3]. IN THIS WORK WE HAVE APPLIED A MIXTURE OF PYROGALLOL AND CUSO4 FOR IN-SITU GENERATION OF CU (I) AND SYNTHESIZED A VARIETY OF 1, 2, 3-TRIAZOLES AT ROOM TEMPERATURE WITH GOOD TO EXCELLENT YIELDS.

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APA: Copy

MIRJALILI, B.F., BAMONIRI, A., & ASADI, M.. (2014). CUSO₄/PYROGALLOL SYSTEM PROMOTED SYNTHESIS OF 1, 2, 3-TRIAZOLES VIA CLICK REACTION. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/913720/en

Vancouver: Copy

MIRJALILI B.F., BAMONIRI A., ASADI M.. CUSO₄/PYROGALLOL SYSTEM PROMOTED SYNTHESIS OF 1, 2, 3-TRIAZOLES VIA CLICK REACTION. 2014. Available from: https://sid.ir/paper/913720/en

IEEE: Copy

B.F. MIRJALILI, A. BAMONIRI, and M. ASADI, “CUSO₄/PYROGALLOL SYSTEM PROMOTED SYNTHESIS OF 1, 2, 3-TRIAZOLES VIA CLICK REACTION,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2014, [Online]. Available: https://sid.ir/paper/913720/en

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