THE EFFECT OF ANION ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS

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NOTASH BEHROUZ; SAFARI NASSER; Darzi Nezhad Khodabakhsh

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Seminar: IRANIAN INORGANIC CHEMISTRY CONFERENCE
Year:2014 | Issue:16

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Title

THE EFFECT OF ANION ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS

Author(s)

NOTASH BEHROUZ | SAFARI NASSER | Darzi Nezhad Khodabakhsh | Issue Writer Certificate

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Abstract

THE CRYSTAL ENGINEERING OF COORDINATION POLYMERS AND METALLO-SUPRAMOLECULAR ARCHITECTURES HAS BEEN STUDIED EXTENSIVELY DUE TO THEIR STRUCTURAL VERSATILITY, UNIQUE PROPERTIES, AND APPLICATIONS IN DIFFERENT AREAS OF SCIENCE, SUCH AS MATERIALS AND NANOTECHNOLOGY [1]. SINCE THE ROLE OF THE ANION HAS EMERGED AS AN IMPORTANT CONSIDERATION IN ENGINEERING NEW SUPRAMOLECULAR MATERIALS [2-3], WE TURNED OUR ATTENTION TO THE EFFECT OF DIFFERENT ANIONS ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS IN THE SELF-ASSEMBLY PROCESS WITH BRIDGING PYRIDINE SCHIFF-BASE LIGAND (L). IN THIS REGARD, THREE COORDINATION COMPOUNDS [CD(M-L)(M-I)2]N (1), [CD(M-L)( M-SCN)2]N (2), [CD(M-L)( M-OAC)(OAC). CH3OH]N (3) WERE OBTAINED FROM RELATED CADMIUM(II) SALTS AND PYRIDINE SCHIFF-BASE LIGAND (L) (FIG. 1). THESE COMPLEXES HAVE BEEN CHARACTERIZED BY SPECTROSCOPIC METHODS AS WELL AS X-RAY STRUCTURAL ANALYSIS. IN THE CASE OF IODIDE AND THIOCYANATE ANIONS, 2D RHOMBIC (1) AND RECTANGULAR GRID (2) STRUCTURAL MOTIFS WERE CONSTRUCTED, RESPECTIVELY. WHEN WE USE ACETATE ANION, 1D LADDER STRUCTURAL MOTIF WAS OBTAINED (3).

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APA: Copy

NOTASH, BEHROUZ, SAFARI, NASSER, & Darzi Nezhad, Khodabakhsh. (2014). THE EFFECT OF ANION ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS. IRANIAN INORGANIC CHEMISTRY CONFERENCE. SID. https://sid.ir/paper/914196/en

Vancouver: Copy

NOTASH BEHROUZ, SAFARI NASSER, Darzi Nezhad Khodabakhsh. THE EFFECT OF ANION ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS. 2014. Available from: https://sid.ir/paper/914196/en

IEEE: Copy

BEHROUZ NOTASH, NASSER SAFARI, and Khodabakhsh Darzi Nezhad, “THE EFFECT OF ANION ON THE STRUCTURAL MOTIFS OF CADMIUM (II) COORDINATION POLYMERS,” presented at the IRANIAN INORGANIC CHEMISTRY CONFERENCE. 2014, [Online]. Available: https://sid.ir/paper/914196/en

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