CONSTRUCTION OF SELECTIVE POTENTIOMETRIC SENSOR FOR MERCURY BY ION IMPRINTED POLYMER COATED-WIRE ELECTRODE

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SHABANI R.; FIROOZI S.

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Seminar: IRANIAN CHEMISTRY CONGRESS
Year:2013 | Issue:16

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Title

CONSTRUCTION OF SELECTIVE POTENTIOMETRIC SENSOR FOR MERCURY BY ION IMPRINTED POLYMER COATED-WIRE ELECTRODE

Author(s)

SHABANI R. | FIROOZI S. | Issue Writer Certificate

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Abstract

ION IMPRINTING IS A UNIQUE TECHNIQUE USED FOR PREPARING POLYMERS WITH SYNTHETIC RECOGNITION SITES HAVING A PREDETERMINED SELECTIVITY FOR ANALYTES OF INTEREST. IN RECENT YEARS, ION IMPRINTED POLYMERS (IIPS) HAVE GAINED WIDE ACCEPTANCE AS NEW ION RECOGNITION MATERIALS IN CHEMICAL SENSORS. POTENTIOMETRIC TECHNIQUE IS ALSO WELL-KNOW VERSATILE, SIMPLE, RAPID AND INEXPENSIVE METHOD FOR DETERMINATION OF TARGET ION. POTENTIOMETRIC TECHNIQUE IS ANOTHER APPROACH TO ELECTROCHEMICAL TRANSDUCTION OF ION SELECTIVE SENSORS BASED ON IIP.WITH THE POTENTIOMETRIC TRANSDUCTION MODE, POLYMERIC MEMBRANE ION SELECTIVE ELECTRODES (ISES) HAVE FOUND WIDESPREAD USE IN INDUSTRIAL, CLINICAL AND ENVIRONMENTAL ANALYSIS OWING TO THEIR ADVANTAGES SUCH AS GOOD SELECTIVITY, LOW COST OF PREPARATION, RAPIDITY AND EASINESS OF MEASUREMENT AND HIGH RELIABILITY.IN THIS STUDY, A POLYMERIC MEMBRANE ION-SELECTIVE ELECTRODE FOR DETERMINATION OF MERCURY (II) IS DESCRIBED. IT IS BASED ON A ION IMPRINTED POLYMER FOR ION RECOGNITION, WHICH CAN BE SYNTHESIZED WITH MERCURY (II) ACETATE AS MERCURY SALT, METHACRYLIC ACID AND 1, 3_DIMETHYLBARBITURIC ACID AS FUNCTIONAL MONOMERS, ETHYLENE GLYCOL DIMETHACRYLATE AS CROSS-LINKING AGENT AND AZOBISISOBUTYRONITRILLE AS AN INITIATOR. AND A NEW COATED WIRE ELECTRODE HAS BEEN DEVELOPED AS A MERCURY ION-SELECTIVE SENSOR. THE OPTIMIZED MEMBRANE INCORPORATING DOP, PVC AND IIP WAS DIRECTLY COATED ON THE SURFACT OF A PLATINUM WIRE ELECTRODE. THE EFFECTS OF THE PH AND POSSIBLE INTERFERING IONS WERE INVESTIGATED AND THE OPTIMIZED CONDITIONS FOR ELECTROD WERE EVALUATED.

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APA: Copy

SHABANI, R., & FIROOZI, S.. (2013). CONSTRUCTION OF SELECTIVE POTENTIOMETRIC SENSOR FOR MERCURY BY ION IMPRINTED POLYMER COATED-WIRE ELECTRODE. IRANIAN CHEMISTRY CONGRESS. SID. https://sid.ir/paper/914256/en

Vancouver: Copy

SHABANI R., FIROOZI S.. CONSTRUCTION OF SELECTIVE POTENTIOMETRIC SENSOR FOR MERCURY BY ION IMPRINTED POLYMER COATED-WIRE ELECTRODE. 2013. Available from: https://sid.ir/paper/914256/en

IEEE: Copy

R. SHABANI, and S. FIROOZI, “CONSTRUCTION OF SELECTIVE POTENTIOMETRIC SENSOR FOR MERCURY BY ION IMPRINTED POLYMER COATED-WIRE ELECTRODE,” presented at the IRANIAN CHEMISTRY CONGRESS. 2013, [Online]. Available: https://sid.ir/paper/914256/en

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