X-RAY CRYSTAL STRUCTURAL STUDIES OF COPPER (II) COMPLEX OF ASYMMETRIC BIS (THIOSEMICARBAZONE) LIGAND

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HOSSEINPOOR SARA; HOSSEINI YAZDI SEYED ABOLFAZL; hosseinpoor zahra

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Seminar Paper

Paper Information

Seminar: SYMPOSIUM OF CRYSTALLOGRAPHY AND MINERALOGY OF IRAN
Year:2016 | Issue:23

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Title

X-RAY CRYSTAL STRUCTURAL STUDIES OF COPPER (II) COMPLEX OF ASYMMETRIC BIS (THIOSEMICARBAZONE) LIGAND

Author(s)

HOSSEINPOOR SARA | HOSSEINI YAZDI SEYED ABOLFAZL | hosseinpoor zahra

Keywords

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Abstract

ASYMMETRIC, POTENTIALLY TETRADENTATE LIGAND H2L1.2MEOH IS FORMED BY SUBSEQUENT CONDENSATION A 4- CHLOROPHENYL THIOSEMICARBAZIDE AND 4-BROMOPHENYL THIOSEMICARBAZIDE ON 2- [3- (2-FORMYL PHENOXY) PROPOXY] BENZALDEHYDE. THE MIXED BIS (THIOSEMICARBAZONE) AND ITS COPPER (II) COMPLEX HAVE BEEN CHARACTERIZED WITH X-RAY CRYSTALLOGRAPHY. LIGAND LOSES HYDRAZINIC HYDROGEN ATOMS UPON COORDINATION AND ACT AS DIANIONIC TETRADENTATE DONORS. IN [CUL1].MEOH COMPLEX METAL CENTER IS COORDINATED BY TWO IMINE NITROGEN ATOMS AND TWO SULFUR ATOMS WITH A DISTORTED SQUARE PLANAR COORDINATION GEOMETRY. UNIT CELL DIMENSIONS OF [CUL1].MEOH AND H2L1.2MEOH ARE A=19.107 (4) Å, B=9.110 (2) Å, C=19.966 (4) Å, A=90°, B=106.93 (2) °, G=90° AND A=9.2206 (6) Å, B=12.2704 (5) Å, C=30.985 (2) Å, A=90°, B=90O, G=90O, RESPECTIVELY.

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APA: Copy

HOSSEINPOOR, SARA, HOSSEINI YAZDI, SEYED ABOLFAZL, & hosseinpoor, zahra. (2016). X-RAY CRYSTAL STRUCTURAL STUDIES OF COPPER (II) COMPLEX OF ASYMMETRIC BIS (THIOSEMICARBAZONE) LIGAND. SYMPOSIUM OF CRYSTALLOGRAPHY AND MINERALOGY OF IRAN. SID. https://sid.ir/paper/926431/en

Vancouver: Copy

HOSSEINPOOR SARA, HOSSEINI YAZDI SEYED ABOLFAZL, hosseinpoor zahra. X-RAY CRYSTAL STRUCTURAL STUDIES OF COPPER (II) COMPLEX OF ASYMMETRIC BIS (THIOSEMICARBAZONE) LIGAND. 2016. Available from: https://sid.ir/paper/926431/en

IEEE: Copy

SARA HOSSEINPOOR, SEYED ABOLFAZL HOSSEINI YAZDI, and zahra hosseinpoor, “X-RAY CRYSTAL STRUCTURAL STUDIES OF COPPER (II) COMPLEX OF ASYMMETRIC BIS (THIOSEMICARBAZONE) LIGAND,” presented at the SYMPOSIUM OF CRYSTALLOGRAPHY AND MINERALOGY OF IRAN. 2016, [Online]. Available: https://sid.ir/paper/926431/en

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