Permeation tests were conducted by Devanathans electrochemical method and a newly invented electro-vacuum method. Experiments illustrated that as the microstructure changed, the diffusion constant, D, changed. The steel SS 4360 when quenched, decreased its D value by 3.7 times that of the original plate. Comparing the behavior of AISI 4340 with API X52, it is noted that the D value of the latter alloy is 2.23 times that of API X52, due to the presence of less C and Ni content. Ingress of hydrogen increased with the reduction of voltage and pH. For alloy SS 4360, when the charging voltage was dropped by -400 mv,the D value increased by 62%. Thickness would not have a realistic effect, but cold work reduced D. The same alloy when cold worked by 72%, its D value decreased by 15%.The difference in D measuredby the two methods of permeation was due to the variation in material, apparatus design and operation. Hydrogen degradation during stress corrosion and corrosion fatigue tests is one of the two processes of crack propogation. Immersion, dynamic polarization, stress corrosion (dynamic and static), corrosion fatigue tests, cathodic protection and fractographic studies were conducted in seawater and sour (hydrogen sulfide generatedby sulfate reducing bacteria) environments. Overall, it was concluded that with regards to Nemests equation, as the partial pressure of hydrogen increased, the value of D increased. Furthermore, the speed of hydrogen diffusion increased. In the sour environment, the overtaking mechanism of failure was found to be hydrogen embrittlement rather than anodic dissolution.