The limitation on allowable temperature range of nickel cadmium (Ni-Cd) requires the designers to analysis their thermal behavior with respect to its parameters. Ni-Cd batteries are use in many applications including cordless and portable devices, emergency and standby power, telecommunication equipments, photovoltaic systems, electric vehicle, satellite and spacecraft and power plant supporting equipments. To date, most studies have utilized averaged properties in their analysis. In addition, the chemical reaction effect on the source term has been neglected. The purpose of this study is to numerically investigate the transient thermal behavior of Ni-Cd batteries. The governing equation is the transient and non-linear differential energy equation subjected to non-linear radiation boundary conditions and source term. In formulation of the governing differential energy equation, the Ni-Cd properties (K, C, p) are not constant and the chemical characteristic of the Ni-Cd batteries, source term, vary with location and time. Calculated thermal characteristic of each battery is then compared to experimental results.