KINETIC STUDY OF THERMAL DEGRADATION OF DI-, CHLORODI- AND TRIORGANOTIN(IV) COMPLEXES OF 2-[(2,6-DICHLORODIPHENYL)AMINO]BENZENE ACETATE

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MASOOD H.; YAQUB S.; ALI S.; SHAH ZADI S.; AHMED F.

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Journal Paper

Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2006 | Volume:3 | Issue:2 Page(s): 151-156

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Title

KINETIC STUDY OF THERMAL DEGRADATION OF DI-, CHLORODI- AND TRIORGANOTIN(IV) COMPLEXES OF 2-[(2,6-DICHLORODIPHENYL)AMINO]BENZENE ACETATE

Author(s)

Keywords

ORGANOTIN(IV) COMPLEXES

THERMAL DEGRADATION KINETICS

Abstract

The organotin complexes of the general formulae R2SnL2, R2SnLCl and R3SnL where R = C4H9, C6H5, and C7H7 and L = 2-[(2,6-dichlorodiphenyl)amino]benzene acetate, were subjected to thermal decomposition by thermogravimetric analysis (TGA). The decomposition of these compounds occurs mostly in two steps. Kinetic parameters such as order of reaction (n), activation energy (Ea), enthalpy (DH‡) and entropy (DS‡) of activation were calculated by using the Coats and Horowitz methods. The calculated values are in good agreement with observed TG values that confirm the structural integrity of the complexes.

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APA: Copy

MASOOD, H., YAQUB, S., ALI, S., SHAH ZADI, S., & AHMED, F.. (2006). KINETIC STUDY OF THERMAL DEGRADATION OF DI-, CHLORODI- AND TRIORGANOTIN(IV) COMPLEXES OF 2-[(2,6-DICHLORODIPHENYL)AMINO]BENZENE ACETATE . JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 3(2), 151-156. SID. https://sid.ir/paper/282078/en

Vancouver: Copy

MASOOD H., YAQUB S., ALI S., SHAH ZADI S., AHMED F.. KINETIC STUDY OF THERMAL DEGRADATION OF DI-, CHLORODI- AND TRIORGANOTIN(IV) COMPLEXES OF 2-[(2,6-DICHLORODIPHENYL)AMINO]BENZENE ACETATE . JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2006;3(2):151-156. Available from: https://sid.ir/paper/282078/en

IEEE: Copy

H. MASOOD, S. YAQUB, S. ALI, S. SHAH ZADI, and F. AHMED, “KINETIC STUDY OF THERMAL DEGRADATION OF DI-, CHLORODI- AND TRIORGANOTIN(IV) COMPLEXES OF 2-[(2,6-DICHLORODIPHENYL)AMINO]BENZENE ACETATE ,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 3, no. 2, pp. 151–156, 2006, [Online]. Available: https://sid.ir/paper/282078/en

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