REFRACTIVE INDEX AND MOLAR REFRACTIVITY OF BENZONITRILE, CHLOROBENZENE, BENZYL CHLORIDE AND BENZYL ALCOHOL WITH BENZENE AT T=298.15, 303.15, 308.15 AND 313.15 K

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SHUKLA R.K.; MISRA PREETI; SHARMA SWETA; TOMAR NAGENDRA; JAIN PRATIMA

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Paper Information

Journal: JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS) Year:2012 | Volume:9 | Issue:6 Page(s): 1033-1043

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Title

REFRACTIVE INDEX AND MOLAR REFRACTIVITY OF BENZONITRILE, CHLOROBENZENE, BENZYL CHLORIDE AND BENZYL ALCOHOL WITH BENZENE AT T=298.15, 303.15, 308.15 AND 313.15 K

Author(s)

SHUKLA R.K. | MISRA PREETI | SHARMA SWETA | TOMAR NAGENDRA | JAIN PRATIMA

Keywords

BINARY LIQUID

REFRACTIVE INDEX

LORENTZ

REFRACTIVITY

ASSOCIATION CONSTANT

REDLICH

MCALLISTER

Abstract

Densities and refractive indices were measured for the binary liquid mixtures formed by benzonitrile, chlorobenzene, benzyl chloride, and benzyl alcohol with benzene at (T=298.15, 303.15, 308.15 and 313.15 K) and atmospheric pressure over the whole concentration range. The Lorentz–Lorentz mixing rule, the Ramaswami and Anbananthan model, and the model devised by Glinski were used to study the refractive index and molar refractivity. These results have been discussed to study the type of mixing behavior between the mixing molecules. The measured data were fitted to the Redlich–Kister polynomial relation to estimate the binary coefficients and standard errors. Furthermore, the McAllister multibody interaction model is used to correlate the binary refractive index with the experimental findings. It is observed that molar refractivity, molecular interaction, and association constant can be better understood from these models.

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APA: Copy

SHUKLA, R.K., MISRA, PREETI, SHARMA, SWETA, TOMAR, NAGENDRA, & JAIN, PRATIMA. (2012). REFRACTIVE INDEX AND MOLAR REFRACTIVITY OF BENZONITRILE, CHLOROBENZENE, BENZYL CHLORIDE AND BENZYL ALCOHOL WITH BENZENE AT T=298.15, 303.15, 308.15 AND 313.15 K. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), 9(6), 1033-1043. SID. https://sid.ir/paper/282846/en

Vancouver: Copy

SHUKLA R.K., MISRA PREETI, SHARMA SWETA, TOMAR NAGENDRA, JAIN PRATIMA. REFRACTIVE INDEX AND MOLAR REFRACTIVITY OF BENZONITRILE, CHLOROBENZENE, BENZYL CHLORIDE AND BENZYL ALCOHOL WITH BENZENE AT T=298.15, 303.15, 308.15 AND 313.15 K. JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS)[Internet]. 2012;9(6):1033-1043. Available from: https://sid.ir/paper/282846/en

IEEE: Copy

R.K. SHUKLA, PREETI MISRA, SWETA SHARMA, NAGENDRA TOMAR, and PRATIMA JAIN, “REFRACTIVE INDEX AND MOLAR REFRACTIVITY OF BENZONITRILE, CHLOROBENZENE, BENZYL CHLORIDE AND BENZYL ALCOHOL WITH BENZENE AT T=298.15, 303.15, 308.15 AND 313.15 K,” JOURNAL OF THE IRANIAN CHEMICAL SOCIETY(JICS), vol. 9, no. 6, pp. 1033–1043, 2012, [Online]. Available: https://sid.ir/paper/282846/en

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