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Information Journal Paper

Title

Synthesis and Investigation of Photophysical Properties of Zinc Complexes with Schiff Base Ligands Derived from ortho-Vanillin

Pages

  159-169

Abstract

 Schiff base ligands provide a platform for the development of suitable ligands for coordination to transitional metal ions. In this research, synthesis, characterization, and photophysical properties of three zinc complexes with Schiff bases ligands derived from ortho-vanillin are investigated. 6-Methoxy-2-[(E)-Aryliminomethyl]-phenol (Aryl = Phenyl; 2, 6-dimethyl; 2, 6-diisopropylphenyl), comprising L1-3 ligands, and the corresponding zinc complexes [Zn(Ln)2, n=1-3] were synthesized. The complexes were characterized using infrared, ultraviolet, and nuclear magnetic resonance spectroscopy techniques. The complexes show interesting photophysical properties. In the absorption spectra of the zinc complexes, the observed high-intensity peaks are attributed to the intra ligand p-p < /em>*, originating from ortho-vanillin and aromatic rings. All three zinc complexes feature emission bands in dichloromethane, while only two metal complexes are emissive in the solid-state.

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  • Cite

    APA: Copy

    Neshat, Abdollah, & Shiri, Elmira. (2020). Synthesis and Investigation of Photophysical Properties of Zinc Complexes with Schiff Base Ligands Derived from ortho-Vanillin. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), 38(4 (94) ), 159-169. SID. https://sid.ir/paper/385464/en

    Vancouver: Copy

    Neshat Abdollah, Shiri Elmira. Synthesis and Investigation of Photophysical Properties of Zinc Complexes with Schiff Base Ligands Derived from ortho-Vanillin. NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN)[Internet]. 2020;38(4 (94) ):159-169. Available from: https://sid.ir/paper/385464/en

    IEEE: Copy

    Abdollah Neshat, and Elmira Shiri, “Synthesis and Investigation of Photophysical Properties of Zinc Complexes with Schiff Base Ligands Derived from ortho-Vanillin,” NASHRIEH SHIMI VA MOHANDESI SHIMI IRAN (PERSIAN), vol. 38, no. 4 (94) , pp. 159–169, 2020, [Online]. Available: https://sid.ir/paper/385464/en

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