NANOSTARCH-BASED POLYMER AS A NEW CATALYST FOR HECK CROSS-COUPLING REACTION

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HASANPOUR GALEHBAN MORTEZA; HASSANPOUR AKBAR

مرکز اطلاعات علمی Scientific Information Database (SID) - Trusted Source for Research and Academic Resources

Seminar Paper

Paper Information

Seminar: IRANIAN SEMINAR OF ORGANIC CHEMISTRY
Year:2014 | Issue:22

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Title

NANOSTARCH-BASED POLYMER AS A NEW CATALYST FOR HECK CROSS-COUPLING REACTION

Author(s)

HASANPOUR GALEHBAN MORTEZA | HASSANPOUR AKBAR | Issue Writer Certificate

Keywords

PALLADIUM CATALYST

STARCH NANOPARTICLES

HECK REACTION

CROSS-COUPLING REACTION

Abstract

HECK REACTION IS ONE OF THE MOST VERSATILE AND USEFUL TOOLS IN ORGANIC SYNTHESIS [1]. PALLADIUM (PD) IS ONE OF THE MOST USEFUL TRANSITION METAL CATALYSTS FOR THE SYNTHESIS OF ORGANIC COMPOUNDS, ESPECIALLY CARBON–CARBON CROSS-COUPLING REACTIONS. HOWEVER, ITS USE IS LIMITED IN HOMOGENEOUS REACTION SYSTEMS DUE TO DIFFICULTIES IN SEPARATING THE PALLADIUM CATALYST AND LIGAND FROM THE FINAL PRODUCT AND RECYCLING THE CATALYST. ACCORDINGLY, MANY VARIETIES OF SOLID-SUPPORTED PALLADIUM CATALYSTS SUCH AS SILICA, CHITOSAN, CELLULOSE AND SO HAVE BEEN DEVELOPED BY IMMOBILIZING [2, 3]. IN RECENT YEARS, EFFORTS HAVE BEEN DEVOTED TO USE SEVERAL BIOPOLYMERS, AS SUPPORTS FOR CATALYTIC APPLICATIONS [4]. IN THIS STUDY, WE HAVE SYNTHESIZED A SIMPLE HETEROGENEOUS PALLADIUM COMPLEX WHICH IS SUCCESSFULLY EMPLOYED AS AN EXCELLENT CATALYST FOR HECK CROSS-COUPLING REACTIONS. A VARIETY OF SUBSTRATES, BOTH ELECTRON-RICH AND ELECTRON-POOR OLEFINS, WERE CONVERTED SMOOTHLY TO THE TARGETED PRODUCTS IN HIGH YIELDS.

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APA: Copy

HASANPOUR GALEHBAN, MORTEZA, & HASSANPOUR, AKBAR. (2014). NANOSTARCH-BASED POLYMER AS A NEW CATALYST FOR HECK CROSS-COUPLING REACTION. IRANIAN SEMINAR OF ORGANIC CHEMISTRY. SID. https://sid.ir/paper/913934/en

Vancouver: Copy

HASANPOUR GALEHBAN MORTEZA, HASSANPOUR AKBAR. NANOSTARCH-BASED POLYMER AS A NEW CATALYST FOR HECK CROSS-COUPLING REACTION. 2014. Available from: https://sid.ir/paper/913934/en

IEEE: Copy

MORTEZA HASANPOUR GALEHBAN, and AKBAR HASSANPOUR, “NANOSTARCH-BASED POLYMER AS A NEW CATALYST FOR HECK CROSS-COUPLING REACTION,” presented at the IRANIAN SEMINAR OF ORGANIC CHEMISTRY. 2014, [Online]. Available: https://sid.ir/paper/913934/en

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