Water contaminated to heavy metals pollution is concerned for health problem because of its toxicity and long term persistent in environment. In this investigation the heavy metals concentration of (Fe, Cu, Zn, Pb, Cr, Cd, Ni) and pesticides paraquat, 2-4-D, imidacluprid were determined at four study station in river after yamchi dam Ardabil Provence. The heavy metals sample were prepared by liquid-liquid extraction MIBK/APDC method the measured by atomic absorption. The residual pesticide were determined by capillary Colum gas chromatography (GC) with ECD detector. The result showed that the heavy metal level were low and most of them were under detectable concentration of atomic absorption equipment. The mean concentration of Fe, Cu, Zn, Cr and Pb 0. 385± 0. 004, 0. 091± 0. 014, 0. 087± 0. 012, 0. 023± 0. 001, 0. 046± 0. 011mg/ l. Cluster Analysis determined 3 different classes of heavy metals which com suggest that the soirees of these heavy metal are difference. The level residual pesticide paraquat and imidacluprid were in samples were very Lowe and the mean concentration of 2-4-D pesticide were 0. 6± 0. 23 µ g/l.